Cyclic Voltammetric Studies of Hydroxytriazenes in Britton-Robinson Buffer and KCl as Supporting Electrolyte at 298 K

In view of the fact that hardly any cyclic voltammetric studies for hydroxytriazenes are available in the literature, the present investigation is an attempt to perform the study to understand redox mechanism of hydroxytriazenes based on 2-methyl5-chloroaniline and 2-trifluoromethyl-5-chloroaniline.The present work deals with the electrochemical studies of substituted aniline based hydroxytriazenes in acidic and Basic media using cyclic voltammetry which elucidate the tentative mechanism and products of electrode processes. The studies includes cyclic voltammetric of ten hydroxytriazenes under various condition such as 1×10-4, KCl as supporting electrolyte, BR buffer at varying pH values from 4,7 and 9. The studies indicate that hydroxytriazenes are reducible under given condition and their electrochemical mechanism can lead to understand the mechanism under biological condition. For irreversibility of any reaction, no reverse peak is obtained. All the synthesised ligands have only one peak.no reverse peak is obtained in most of the compounds.so we proposed that the process is irreversible.