ali naghizadeh
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امروزه تغییرات جهانی اقلیم به عنوان یکی از بزرگترین تهدیدات تنوع زیستی که برای اقتصاد جوامع انسانی و توسعه اجتماعی بسیار حیاتی است، مطرح می باشد. درک آنکه تغییر اقلیم چگونه بر تنوع زیستی و حیات وحش در سرتاسر جهان تاثیرگذار است مساله ای ضروری و حیاتی است. شروع خشکسالی به طور معمول با کاهش بارندگی همراه است که این مرحله به خشکسالی هواشناسی موسوم است. با کمبود بارش و توزیع نامناسب آن، رطوبت خاک کاهش یافته و رویش گیاهان مرتعی و سایر گیاهان تحت تاثیر قرار می گیرد. در سالهای اخیر استفاده از تصاویر ماهواره ای برای پایش تغییرات پوشش گیاهی و پایش خشکسالی افزایش یافته است. اگرچه تغییر اقلیم بر اکوسیستم و جوامع مختلف تاثیر بسیار زیاد و عمیقی برجای گذاشته که برخی از این اثرات نمایان و برخی هنوز به خوبی شناخته نشده است، ولی به نظر می رسد بیشترین تاثیر بر روی بزرگترین اکوسیستم کره زمین یعنی مراتع رخ داده است. از این رو تحقیق حاضر از تصاویر ماهوارهای و داده های هواشناسی برای بررسی اثرات تغییرات اقلیمی بر پوشش گیاهی مراتع در پارک ملی گلستان استفاده کرده است. به کارگیری روش مقایسه ای بازه های زمانی گذشته و حال برای سناریوی روند تغییرات در اثر تغییر اقلیم و به تبع آن تغییر اکوسیستم پارک ملی گلستان، هدف اصلی مطالعه حاضر می باشد. نتایج حاصل از مدل رگرسیونی نشان می دهد بین دو شاخص SPI و NDVI همبستگی مستقیم وجود دارد و استنباط می شود که به ازای یک واحد تغییر در شاخص بارش استاندارد مقدار NDVI به میزان 0.041 تغییر نماید. کلید واژگان: تغییرات اقلیمی، علوفه حیات وحش، تصاویر ماهواره ای، &Rlm، SPIGlobal warming and climate change are among the most important and critical environmental issues of the world in this century. Today, global climate change is one of the biggest threats to biodiversity, which is very vital for the economy of human societies and social development. Therefore, understanding how climate change affects biodiversity and wildlife around the world is a necessary and vital issue. The onset of drought is usually accompanied by a decrease in rainfall, which is known as meteorological drought. With the lack of rainfall and its inappropriate distribution, soil moisture is reduced and the growth of pasture plants and other plants is affected. In recent years, the use of satellite images to monitor vegetation changes and drought monitoring has increased. Although climate change has left a huge and deep impact on different ecosystems and societies, but it seems that the greatest impact has occurred on the largest ecosystem on the planet, i.e., pastures. Therefore, the current research has used satellite images and meteorological data to investigate the effects of climate change on the vegetation of grasslands in Golestan National Park, using the comparative method of past and present time periods. The results of the regression model show that there is a direct correlation between SPI and NDVI, and it is concluded that for one unit change in the standard rainfall index, the value of NDVI changes to 0.041.Keywords: Climate Change, Wildlife Fodder, Satellite Images, SPI
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هدفهدف از این پژوهش تحلیل رابطه بین اقتصاد سایه ای و ارکان رقابت پذیری در کشور ایران است.روشتحقیق حاضر به لحاظ هدف، کاربردی، به لحاظ روش استنتاج، توصیفی- تحلیلی و به لحاظ طرح کلی تحقیق، پس رویدادی است. داده ها با به کارگیری نرم افزار ایویوز از طریق روش مارکوف سویچینگ-ور، مورد تحلیل قرار گرفت.یافته هانتایج نشان داد بین حجم اقتصاد سایه ای و شوک وارده بر ارکان نهاده محور و کارایی محور رقابت پذیری در رژیم یک (دوره رکود) و ارکان کارایی محور و خلاقیت محور رقابت پذیری در رژیم دو (دوره رونق) رابطه معنا داری وجود دارد. معنا داری ارکان نهاده محور در رژیم دو (دوره رونق) و ارکان کارایی محور در رژیم یک (دوره رکود) تایید نشد.نتیجه گیریاگرچه برخی اقتصادهای سایه ای ممکن است اثرات مفیدی برای برخی شهروندان یا حتی اقتصاد رسمی یک کشور داشته باشند، در کل اقتصاد سایه ای به رقابت پذیری کشور آسیب می رساند؛ زیرا اعتماد سرمایه گذاران خارجی به آن کشور و در نتیجه احتمال همکاری آن ها را کاهش می دهد. از سوی دیگر، رقابت پذیری می تواند انگیزه هایی برای وارد کردن عملیات های زیرزمینی به سطح زمین و در نتیجه مبارزه با اقتصاد اعلام نشده ارائه دهد. این تحقیق با استفاده از روش های مناسب اقتصادسنجی، شواهدی پیدا نمود که هر چه یک کشور رقابتی تر باشد، با توجه به شاخص رقابت پذیری جهانی، اقتصاد سایه ای آن کوچک تر می شود.کلید واژگان: اقتصاد سایه ای، رقابت پذیری، مدل مارکوف سویچینگ- ورObjectiveThe economy of developing countries can be recognized by examining the two parts of the formal economy and the informal (shadow) economy. The official sector of the economy can be easily identified in the light of sources, reports and data contained in statistics and censuses, as well as by studying its structure, but the complex and invisible network of the shadow economy must be identified and evaluated with research studies and the role of quantitative and qualitative found this phenomenon in the country's economy. The purpose of this research is the analysis of the relationship between the shadow economy and the elements of competitiveness in Iran.MethodThe current research is applied in terms of purpose, descriptive-analytical in terms of inference method, and post-event in terms of the overall design of the research.ResultsThe results showed that there is a significant relationship between the volume of the shadow economy and the shock on the input-oriented and efficiency-oriented elements of competitiveness in regime one (recession period) and the efficiency-oriented and creativity-oriented elements of competitiveness in regime two (boom period). The significance of input-oriented elements in regime two (boom period) and efficiency-oriented elements in regime one (recession period) was not confirmed.ConclusionConsidering the impact of the size of the shadow economy and the shock on the input-oriented, efficiency-oriented and creativity-oriented elements of competitiveness, in different eras, it is suggested to provide economic platforms, so that we can witness the prosperity of economic indicators in our country. The shadow economy absorbs vital resources from the formal economy and partially prevents the implementation of policies that are necessary for the public interest. Also, the size of the shadow economy of the countries is different and even in some countries it exceeds a quarter of the gross domestic product (GDP). Although some shadow economies may have beneficial effects for some citizens or even the official economy of a country, in general, the shadow economy damages the country's competitiveness; Because it reduces the confidence of foreign investors in that country and, as a result, the possibility of their cooperation. On the other hand, competitiveness can provide incentives to bring underground operations to the surface and thus combat the undeclared economy. Using appropriate econometric methods, this research found evidence that the more competitive a country is, according to the global competitiveness index, its shadow economy becomes smaller (as a percentage of GDP). More precisely, as it was predicted, there is a negative relationship between the shadow economy and global competitiveness, and these results can help the relevant policy makers to curb the shadow economy with appropriate guidance towards increasing competitiveness. The country should help. A country that is interested in ensuring that its shadow economy will not expand; It should improve its competitiveness. Competition is a multidimensional and complex concept, especially when it refers to the national economy. Various indices of competitiveness describe its size and also its dimensions with regard to commercial activity, infrastructure and institutional environments and macroeconomics. At the same time, the competitiveness of a country primarily depends on its economic development, which in turn is affected by several factors. Some of these factors, such as investment, favorable business conditions, legal environment, etc., promote economic development, while others, such as low labor productivity, insufficient qualification of employees, etc., cannot meet the requirements of the labor market. They slow down the speed of economic development. Another thing that was confirmed in this research is the existence of a long-term relationship between the ease of doing business and the size of its shadow economy. In this regard, there is evidence that a country may be able to fight the shadow economy by increasing the ease of doing business. In fact, the shadow economy of a country is the result of the interaction between socio-economic development and its long-term psychological and cultural factors. Some of these factors can be considered and recognized as influential factors only with regard to the shadow economy and competition, but they cannot be significantly affected, at least in the short term. The issues can be considered in terms of the problem of people's mentality. A practical way to deal with the problem of the shadow economy, that is, to reduce the size of this phenomenon, is to promote socio-economic development and ease of doing business. When an economy is growing, ease of doing business also increases a country's competitiveness and most importantly, it helps to form a positive public attitude towards self-efficacy. By increasing business dynamism, developing skills, promoting the adoption of information and communication technology (ICT), increasing market size and infrastructure can be achieved. In addition, restrictive laws and higher living standards may lead to a reduction in the shadow economy. Higher levels of GDP also potentially provide a stronger financial system through macroeconomic stability and can provide more assistance in this area in addition to the guidelines that are formulated to curb unemployment. , because people can do transactions through the formal economy instead of the informal economy. In this regard, increasing exports as a percentage of GDP seems to be a useful tool to reduce the shadow economy. This is while reducing the consequences of the shadow economy through the ease of doing business and increasing GDP per capita and exports (as a percentage of GDP) is definitely a difficult task for the respective countries. However, achieving higher levels of (perceived) competitiveness is not inconceivable. According to the findings of the research, it can be generally stated that competitiveness is the ability of a country to maintain its relative advantages in order to support the economic growth and prosperity of its citizens, and the ease of doing business with the shadow economy are related.Keywords: Shadow Economy, Competitiveness, Markov Switching-VAR
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سابقه و هدف
در تحلیل هم واژگانی فرض بر این است که پربسامدترین واژه ها در مقایسه با واژه های کم بسامد، تاثیر بیشتری بر یک قلمرو موضوعی دارند. هدف از پژوهش حاضر تحلیل هم واژگانی مقالات مروری با موضوع "رایانش ابری" نمایه شده در پایگاه PubMed در بازه زمانی 2009 تا 2022 می باشد.
مواد و روش هاپژوهش حاضر کاربردی است که از تحلیل هم واژگانی برای انجام آن استفاده شده است. جامعه آماری شامل 169 مقاله ی مروری با موضوع "رایانش ابری" نمایه شده در پایگاه PubMed در بازه زمانی 2009 تا 2022 بود. 57 مقاله فاقد کلیدواژه بودند که از مطالعه خارج شدند. داده های مورد نیاز از پایگاه مذکور با وارد کردن واژه "رایانش ابری" در فیلد موضوع بازیابی و در نرم افزار اکسل وارد شد. برای تحلیل هم واژگانی از نرم افزار Voyant Tools استفاده گردید.
یافته هابر اساس نقشه های حاصل شده از تحلیل واژگان، کلیدواژه های محاسبات مه، محاسبات داده، پایگاه ابری، اینترنت اشیا، داده های ابری، چالش ابر، فناوری ابر، سیستم های ابری سیستم های سلامت و ابر، بیشترین همپوشانی را با واژه رایانش ابری داشته اند. ترسیم نقشه های هم واژگانی در مقاطع زمانی مختلف مورد بررسی، تغییرات و پایداری هایی را در مفاهیم و واژه های مرتبط با حوزه اطلاع سنجی نشان می دهد. مفاهیم جدید به عنوان بازترکیبی از واژه های موجود و در تعامل با تحولات و فناوری های جدید پدید آمدند.
نتیجه گیریپربسامدترین واژه در مقالات مروری رایانش ابری در کلیه ی متون نمایه شده در PubMed از میان واژگان محاسبات مه، محاسبات داده، پایگاه ابری، اینترنت اشیا، داده های ابری، چالش ابر، فناوری ابر، سیستم های ابری سیستم های سلامت و ابر بوده است که واژه های "محاسبات داده" و "محاسبات مه" بیشترین همپوشانی را با رایانش ابری داشته اند.
کلید واژگان: مقالات مروری، رایانش ابری، تحلیل هم واژگانی، Voyant ToolsBackground and aimIn co-word analysis, it is assumed that the most frequent words have a greater impact on a subject area compared to the less frequent words. The purpose of the current research is co-word analysis of review articles on the subject of "cloud computing" indexed in the PubMed database in 2009-2022 time period.
Materials and methodsThe current research is applied in terms of nature which utilized co-word analysis to analyze the data. The statistical population included 169 review articles on the topic of "cloud computing" indexed in the PubMed database in 2009 to 2022 period. The total of 57 articles lacked keywords which were excluded from the study. The required data was retrieved from the mentioned database by entering the word "cloud computing" in the subject field which were subsequently added to the Excel software. Voyant Tools software was used for co-word analysis.
FindingsBased on the maps obtained from co-word analysis, keywords fog computing, data computing, cloud database, Internet of Things, cloud data, cloud challenge, cloud technology, cloud systems, health systems and cloud overlapped the most with the term cloud computing. Drawing maps of co-word at different time periods under investigation illustrates changes and stability in the concepts and words related to the field of informatics. New concepts emerged as a recombination of existing words interacting with developments and new technologies.
ConclusionThe most frequent word in cloud computing review articles in all the texts indexed in PubMed among the words cloud computing, data computing, cloud database, Internet of Things, cloud data, cloud challenge, cloud technology, cloud systems , has been health and cloud systems in which the terms "data computing" and "fog computing" overlaped the most with cloud computing.
Keywords: Review Articles, Cloud Computing, Co-Word Analysis, Voyant Tools -
سابقه و هدف
مطالعه ای به منظور بررسی تاثیر روش های مختلفعمل آوری شیمیایی (پر اکسید هیدروژن و هیدروکسید سدیم) و بیولوژیکی (باکتری باسیلوس سابتیلیس و قارچ آسپرژیلوس نایجر) بر ترکیب شیمیایی، تجزیه پذیری شکمبه ای، فراسنجه های تولید گاز و قابلیت هضم کاه کینوا در قالب طرح کاملا تصادفی انجام شد.
مواد و روش هاکاه کینوا از مزارع اطراف شهرستان آشخانه (خراسان شمالی) جمع آوری شده است و سپس به آزمایشگاه تغذیه دام دانشگاه گنبد کاووس انتقال داده می شود. نمونه های کاه تهیه شده در مجاورت هوا خشک شد و به ابعاد 5-2 سانتی متر خرد و در کیسه های 3 کیلویی برای اعمال تیمارهای مختلف نگهداری شدند. تیمارهای آزمایشی شامل: 1) کاه کینوا بدون هیچ گونه افزودنی (شاهد)، 2) کاه کینوا عمل آوری شده با هیدروکسید سدیم، 3) کاه کینوا عمل آوری شده با پراکسید هیدروژن، 4) کاه کینوا عمل آوری شده با باکتری باسیلوس سابتیلیس و 5) کاه کینوا عمل آوری شده با قارچ آسپرژیلوس نایجر، بودند. به منظور عمل آوری بقایای کاه کینوا با هیدروکسید سدیم، 50 گرم از این ماده در یک لیتر آب مقطر حل شده و بر روی یک کیلوگرم ماده خشک بقایا اسپری شد. این مخلوط به خوبی هم زده شد. سپس درون کیسه های پلاستیکی 2 لایه ریخته شده و به خوبی فشرده گردید. در عمل آوری با پراکسید هیدروژن، ابتدا نمونه های بقایا با هیدروکسید سدیم پیش تیمار شدند. بدین صورت که 100 گرم هیدروکسید سدیم در 5/0 لیتر آب حل شد. سپس این محلول به 4 لیتر آب افزوده و روی 2 کیلوگرم از بقایای خردشده اضافه شد. نیم ساعت بعد، 114 میلی لیتر آب اکسیژنه با درجه خلوص 35 درصد در نیم لیتر آب حل شده و به این مخلوط اضافه شد. این مخلوط به خوبی هم زده شد. بقایا درون کیسه های پلاستیکی 2 لایه ریخته شده و به خوبی فشرده و وکیوم شدند. کیسه ها به مدت 18 روز در شرایط بی هوازی نگهداری شدند. به منظور عمل آوری بیولوژیکی، فعال سازی ویال های لیوفیلیزه و تهیه کشت آغازگر از باکتری و قارچ به ترتیب در محیط های MRS- broth در دمای 37 درجه سانتیگراد وPDA در دمای 25 درجه سانتیگراد انجام شد. پس از آن به هر کیلوگرم از کاه کینوا، یک لیتر از ترکیب آب مقطر و کشت آغازگر (حاوی حداقل 105 واحد تشکیل کلنی در میلی لیتر باکتری یا قارچ) اضافه شدند. مخلوط حاصل در نایلون پلاستیکی به مدت 21 روز در دمای 25 درجه سانتیگراد جهت فرآیند تخمیر نگهداری شدند. پس از این مدت، کیسه ها بازشده و در معرض هوا خشک شدند. پس از عمل آوری، ترکیب شیمیایی نمونه ها با استفاده از روش های استاندارد تعیین شد. آزمایش تجزیه پذیری با استفاده از تکنیک کیسه های نایلونی انجام شد. آزمون تولید گاز برای برآورد فراسنجه های تولید گاز استفاده شد. قابلیت هضم برون تنی نمونه ها با استفاده از روش کشت بسته انجام شد.
یافته هانتایج نشان داد که بین تیمارهای عمل آوری شده از نظر ترکیب شیمیایی (ماده خشک، خاکستر، ماده آلی و پروتئین خام) اختلاف معنی داری وجود داشت (05/0>P). بالاترین مقدار ماده خشک مربوط به تیمار شاهد و پایین ترین مقدار مربوط به پراکسید هیدروژن بود. در بین تیمارهای عمل آوری شده شیمیایی، تیمارهای عمل آوری شده با هیدروکسید سدیم بالاتر و تیمارهای عمل آوری شده با پراکسید هیدروژن پایین تری مقدار خاکستر خام را داشتند. روش های مختلف عمل آوری تاثیر معنی داری بر پتانسیل و نرخ تولید گاز داشتند (05/0>P). تیمارهای عمل آوری شده با شاهد و قارچ بالاترین و تیمار هیدروکسید سدیم پایین ترین پتانسیل تولید گاز را داشتند. عمل آوری با هیدروکسید سدیم و پراکسید هیدروژن به طور معنی داری قابلیت هضم ماده خشک و ماده آلی را افزایش دادند (05/0>P). تیمار عمل آوری شده با باکتری پایین ترین قابلیت هضم، عامل تفکیک و تولید پروتئین میکروبی را داشت (05/0>P).
نتیجه گیریبه طور کلی، نتایج حاصل از این مطالعه نشان داد که عمل آوری با هیدروکسید سدیم و پراکسید هیدروژن تاثیر بیشتری در بهبود ارزش تغذیه ای کاه کینوا داشتند.
کلید واژگان: کاه کینوا، عمل آوری شیمیایی، ترکیب شیمیایی، پراکسید هیدروژنIntroductiona study was carried out to investigate the effect of different treatment methods (chemical and biological) on chemical composition, gas production parameters and digestibility of quinoa straw in a completely randomized design.
Materials and methodsQuinoa straw was collected from Ashkhaneh city (north Khorasan province, Iran), chopped into 2-5cm pieces and prepared for processing. The following treatments were: 1) untreated quinoa straw (control) (CON), 2) CON processed with sodium hydroxide, 3) CON processed with hydrogen peroxide, 4) CON inoculated and fermented with Bacillus Subtilis and 5) CON inoculated and fermented with Aspergillus Niger. Prior to hydrogen peroxide treatment (132 mL of 35% H2O2), samples were pretreated with sodium hydroxide (NaOH, 80 g/kg DM) to attain and maintain a pH of 11.5. For biological processing, activation of lyophilized vials and preparation of starter cultures of bacteria and fungi were done in MRS-broth at 37°C and PDA at 25°C, respectively. After that, one liter of the combination of distilled water and starter culture (containing at least 105 colony forming units per milliliter of bacteria or fungi) was added to each kilogram of quinoa straw.Treated samples were then placed into plastic bags, tied up and stored under anaerobic conditions. Prior to analysis, bags were opened and air dried. Chemical composition of the samples was determined using the standard methods of AOAC. Ruminal degradability trial was carried out using the nylon bag technique. Gas production test was used to estimate gas production parameters. In vitro digestibility of the samples was determined through the batch culture method.
ResultsThe results showed that there was a significant difference between treatments in terms of chemical composition (dry matter, ash, organic matter and crude protein) (P<0.05). In this respect, the highest amount of dry matter was in the control treatment and the lowest in the hydrogen peroxide treatment. Among the chemical treatments, the treatments with sodium hydroxide had the highest and the treatments with hydrogen peroxide had the lowest values of Crude Ash. Different treatment methods had significant effect on gas production potential and rate (P <0.05). Treatments with control and fungi had the highest and sodium hydroxide treatment had the lowest gas production potential. Treatment with sodium hydroxide and hydrogen peroxide significantly increased dry matter and organic matter digestibility (P<0.05). In general, the bacteria had the lowest digestibility, partitioning factor, and microbial protein production.
ConclusionsOverall, the results of this study showed that treatment with sodium hydroxide and hydrogen peroxide had a greater effect on improving the nutritional value of quinoa straw.
Keywords: Quinoa Straw, Chemical Processing, Chemical Composition, Hydrogen Peroxide -
International Journal of Finance and Managerial Accounting, Volume:8 Issue: 30, Summer 2023, PP 361 -375The purpose of this research is the analysis of the relationship between the shadow economy and the elements of competitiveness in developing oil countries. The current research is applied in terms of purpose, descriptive-analytical in terms of inference method, and post-event in terms of the overall design of the research. The final sample used for this study is the data of 72 developing oil countries during the years 2005-2020. The data was analyzed by applying Eviews software through vector panel autoregressive distributed lag model (PARDL) and the Markov switching method. The results showed that in the short term there is a significant relationship between the shadow economy and the input-oriented elements of the developing oil countries, but the significant relationship between the shadow economy and the efficiency-oriented and creativity-oriented elements of the competitiveness of the developing oil countries was not confirmed. Also, in the long term, there is a significant relationship between the shadow economy and the efficiency-oriented and input-oriented elements of the developing oil countries, but the significant relationship between the shadow economy and the creativity-oriented elements of the competitiveness of the developing oil countries was not confirmed. In addition, in the long term, there is a significant relationship between the shadow economy and the index of ease of doing business in developing oil countries, but in the short term, there is a significant relationship between the index of ease of doing business and the shadow economy of oil countriesKeywords: Shadow economy, Competitiveness, Ease of Doing Business
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Background & Aims:
Prevention is the best solution to break the coronavirus disease 2019 (COVID-19) infection chain. The aim of the present study was to investigate the degree of adherence to environmental health parameters for COVID-19 prevention in South Khorasan Province.
Materials and MethodsThis cross-sectional study was performed on 410 residents of South Khorasan in 2021. The data collection instrument containing a researcher-made questionnaire included demographic, knowledge, and performance questions. The validity and reliability of the questionnaire were confirmed, an online questionnaire was prepared, and the questionnaire link was sent via online networks. Data were entered into SPSS version 16 and analyzed using an independent t-test, analysis of variance, and correlation coefficient. P value ≤ 0.05 was considered as the significance level.
ResultsThe results showed that 35.9% and 64.1% of participants were women and men, respectively. A total of 82.9% of people wore masks outdoors, and 83.7% of people washed their hands with sanitizer or soap on a daily basis. Further, statistical analysis revealed no significant relationship between performance and demographic characteristics. However, knowledge was significantly associated with gender, job, and education (P ≤ 0.05).
ConclusionThe participants had poor knowledge and performance, and there was a need to provide education in this regard in order to update COVID-19 knowledge and change the behavior of the general public towards this emerging disease.
Keywords: Knowledge, Environmental health, COVID-19 -
Introduction
Air pollution is the leading environmental risk factor for health. This study aimed to assess heavy metals in Particulate Matter (PM10, PM2.5) and their health impact assessment for a desert city in Iran, Birjand.
Materials and methodsIn this study, the concentrations of PM10 and PM2.5 were measured from September 2019 to March 2020. Measurements were performed once every six days for 24 h using high-volume samplers.
Moreover, health-related effects attributed to the suspended particles were estimated using the AirQ2.2.3.ResultsMean and standard deviation of PM10 and PM2.5 concentrations were 97.5±38.7 μg/m3
and 36.3±19.1 μg/m3, respectively. The mean metal concentrations in PM2.5 were in the Co> Cd> Ce> V order, while the metal concentrations in PM10 were in the Cd> As> Ce>V order. The lowest and highest number of deaths attributed to PM2.5 per 100,000 persons were related to ischemic heart disease (1.73) and chronic respiratory disease (18.35). The highest number of deaths attributed to PM10 per 100,000 persons was related
to chronic bronchitis in adults (35.74).ConclusionThis study revealed that particle-based air pollution negatively affects health as caused by heavy metals, whereas further research is required to determine the effects of bacterial and fungal bioaerosols on human health. Monitoring the elemental composition of atmospheric particles can contribute to better air quality management.
Keywords: Particulate matter, Metals, Air pollution -
Background
COVID-19 has become a global problem. In this case study, the experiences gained from disease control in rural areas are reported.
MethodsAn observational study was done in 2020 in Sistan and Balochestan, the largest province with most rural areas in the southeast of Iran.
ResultsAfter identification of the first patient of Covid-19 in a rural area, three measures were taken including: 1. Diagnosis, screening and treatment of the disease (Incident command post was established and the village was completely quarantined, etc.; 2. Intersectoral coordination for epidemiological management (limiting traffic for people and any gathering); and 3. Identification of any Covid-19 positive cases. The results of these measures showed that after quarantining the village and performing the mentioned actions, the number of patients decreased, and the disease was controlled.
ConclusionQuarantine of the contaminated rural area and people’s traffic routes is one of the most important measures in controlling Covid-19.
Keywords: Rural health, COVID-19, Quarantine, Intersectoral collaboration -
مقایسه شبکه عصبی مصنوعی و رگرسیون خطی چندگانه در پیش بینی کدورت فیلتراسیون شنی کند تصفیه خانه آب طبسزمینه و هدف
کدورت آب تصفیه شده به عنوان یک پارامتر مهم در تعیین کیفیت آب آشامیدنی و یا صنعتی در تمامی تصفیه خانه ها اندازه گیری می شود. از دیر باز با توجه به اهمیت یافتن شیوع عوامل بیماریزا مثل ژیاردیا و کریپتوسپوریدیوم که عامل ایجاد بیماری های خطرناکی همچون اسهال خونی می باشند، رابطه کاهش میزان کدورت و افزایش حذف این میکروارگانیزم ها در مطالعات به اثبات رسیده است.
مواد و روش هادر این مطالعه یک مدل شبکه عصبی مصنوعی و رگرسیون خطی چندگانه در پیش بینی کدورت خروجی از آب تصفیه شده تصفیه خانه شهر طبس توسعه و عملکرد آنها با هم مقایسه گردید. کل جامدات محلول، pH، ، دما و کدورت ورودی به عنوان پارامترهای ورودی مدل ها در پیش بینی ها استفاده شد. بهترین الگوریتم پس انتشار و تعداد نورون برای بهینه سازی معماری مدل تعیین شد.
یافته هانتایج نشان داد که الگوریتم لونبرگ-مارکوارت به عنوان بهترین الگوریتم انتخاب شد و تعداد نورون بهینه نیز 16 تعیین شد. همچنین نتایج تحلیل حساسیت مدل شبکه عصبی نشان داد که کدورت ورودی با مقدار 29 درصد به عنوان مهمترین پارامتر در توسعه مدل شبکه عصبی مصنوعی است.
نتیجه گیرینتایج ضریب همبستگی مدل رگرسیون خطی چندگانه و مدل شبکه عصبی مصنوعی به ترتیب برای داده های آموزش 63/0 و 892/0 و برای داده های تست 60/0 و 8571/0 به دست آمد که نشان از برتری مدل شبکه عصبی مصنوعی در پیش بینی کدورت خروجی از تصفیه خانه آب طبس است.
کلید واژگان: کدورت، تصفیه خانه آب، شبکه عصبی مصنوعی، رگرسیون خطی چندگانه، پیش بینیBackground and purposeThe turbidity of treated water is measured as an important parameter in determining the quality of drinking or industrial water in all treatment plants. Due to the importance of the prevalence of pathogens such as Giardia and Cryptosporidium, which cause dangerous diseases such as dysentery, the relationship between reducing turbidity and increasing the elimination of these microorganisms has been proven in studies.
Materials and methodsIn this study, an artificial neural network (ANN) model and multiple linear regression(MLR) were developed and their performance was compared to predict the turbidity of treated water of Tabas water treatment plant. Total dissolved solids, pH, temperature and input turbidity of raw water were used as input parameters of the models in the predictions. The best backpropagation algorithm and number of neurons were determined to optimize the model architecture.
ResultsThe results showed that the Levenberg–Marquardt algorithm was selected as the best algorithm and the number of optimal neurons was determined to be 16.Also, the results of the sensitivity analysis of the neural network model showed that the input turbidity with a value of 29% is the most important parameter in the development of the ANN model.
ConclusionThe results of correlation coefficient of MLR and ANN models were obtained for training data 0.63 and 0.8921 and for testing data 0.60 and 0.8571, respectively, which show the superiority of ANN model in Predicting the turbidity of the output of Tabas water treatment plant.
Keywords: Turbidity, water treatment, Artificial neural network, multiple linear regression, Prediction -
زمینه و هدف
با وجود پیشرفت های روز افزون بشر در مورد کنترل بیماری ها، هنوز هم لیشمانیوزها یکی از معضلات بهداشتی به شمار می آیند. این مطالعه با هدف تعیین عوامل موثر بر تاخیر در مراجعه موارد ثبت شده مبتلا به لیشمانیوز جلدی از سال 93-1388 در سیستان و بلوچستان انجام گرفت.
روش و مواداین مطالعه توصیفی تحلیلی با مشارکت 2410 نفر از بیماران مبتلا به لیشمانیوز جلدی شهرستان های تابعه دانشگاه های علوم پزشکی زاهدان و ایرانشهر طی سال های 93-1388 انجام گرفت. روش نمونه گیری سرشماری بوده و جمع آوری داده ها با استفاده از پرسشنامه ای دوبخشی شامل متغیرهای دموگرافیک و اطلاعات بیماری صورت گرفت. محاسبات آماری جهت تعیین مهم ترین عوامل موثر بر تاخیر در مراجعه بیماران، توسط نرم افزار SPSS-20 و به روش رگرسیون لجستیک انجام شد.
یافته هامیانگین (انحراف معیار) سن بیماران (4/16) 3/19 سال و اندازه زخم ها (5/1) 7/2 سانتیمتر و تاخیر در مراجعه بیماران به مرکز درمانی (5/52) 7/59 روز بود. تعداد 1509 (6/62%) نفر از بیماران مرد و 2014 (6/83%) نفر از آنها ایرانی بودند. کودکان 730 (3/30%) مورد از بیماران را تشکیل می دادند. پاکستانی ها نسبت به ایرانی ها 70% (01/0>P)، عشایر نسبت به شهرنشینان 83% (02/0=P) و بیماران دارای سابقه ابتلای همزمان سایر اعضای خانواده نسبت به گروه مقابل 39% (02/0=P) احتمال کمتری برای تاخیر در مراجعه داشتند. بیماران ارجاعی توسط مراکز خصوصی به میزان 126% احتمال بیشتری نسبت به بیماران ارجاعی توسط مراکز درمانی دولتی برای تاخیر در مراجعه داشتند (02/0=P). افرادی که دارای زخم خشک بودند نسبت به افرادی که زخم مرطوب داشتند 124% احتمال بیشتری برای تاخیر در مراجعه داشتند (01/0>P).
نتیجه گیریمطالعه نشان داد که تاخیر در مراجعه مبتلایان به بیماری لیشمانیوز جلدی در شهرستان های استان سیستان و بلوچستان نسبتا زیاد بود و ملیت پاکستانی، محل سکونت عشایری، ارجاع از مراکز بهداشتی درمانی دولتی، سابقه ابتلای همزمان سایر اعضای خانواده و زخم به شکل مرطوب، عوامل موثر در کاهش مراجعه با تاخیر بیماران به مراکز درمان سالک شهرستان ها بودند.
کلید واژگان: لیشمانیوز جلدی، تاخیر در مراجعه، کانون های آلودگی، سیستان و بلوچستانBackground and ObjectiveIn despite of the advancements and achievements regarding the control of the diseases, Leishmaniosis is still known as one of the basic health concerns. The objective of this study was to determine the effective factors in the follow-up delay among registered cases infected with Cutaneous Leishmaniosis from 2009 to 2014 in Sistan and Baluchestan province, Iran.
Materials and MethodsParticipants of this analytic descriptive study included 2410 people infected with Cutaneous Leishmaniosis from cities covered by Zahedan and Iran-Shahr Medical Universities from 2009 to 2014. Census sampling method was conducted and data were collected through the two-part questionnaire which included demographic variables and disease information. SPSS software version 20 was used for statistical analysis in order to determine the most important effective factors in patients’ follow-up delay by implementing logistic regression.
ResultsThe mean (SD) patients’ age was 19.3 (16.4) years, the size of the wounds were identified as 2.7 (1.5) centimeter, and patients follow-up delay was 59.7 (52.5) days. As many as 1502 of patients (62.6%) were male, and 2014 (83.6%) were female. 730 patients (30.3%) were kids. Pakis compared with Iranians 70% (P<0.01), nomads compared with urban citizens 83% (P=0.02), and patients with the history of simultaneous infection of other family members compared with the opposite group 39% (P=0.02) had the less possibility of follow-up delay. Patients who were referred from the private centers had 126% higher possibility of follow-up delay than those referred by the state health centers (P=0.02). Patients with the dry wound compared with those with wet wound had higher rate of follow-up (P< 0.01).
ConclusionThe study showed that the delay in follow-up among patients infected by the Cutaneous Leishmaniosis in cities of Sistan and Baluchestan province was relatively high. The effective factors in decreasing the follow-up delays of the patients and treatment seeker included beشing Paki, nomads’ life place, referral from the state health centers, wet wound, and history of the simultaneous infection of the family members.
Keywords: Cutaneous Leishmaniosis, Follow-up delay, Pollution centers, Sistan, Baluchestan -
Iranian Journal of Chemistry and Chemical Engineering, Volume:39 Issue: 4, Jul-Aug 2020, PP 235 -244Antibiotics are discharged into the aqueous environment in various ways. The disposal of wastewater containing antibiotics creates serious environmental problems. Today, given the necessity of using natural materials, natural-based adsorbents have been taken into consideration. Chitosan is a natural polysaccharide derived from the crust of crustaceans of the sea with many useful aspects such as hydrophilicity, biodegradability, and biocompatibility. In this study, after the preparation of chitosan, the effect of various parameters such as pH (3-11), adsorbent dosage (0.25-1g/L), penicillin G concentration (10-70 mg/L), and contact time (5-90 min) in the removal of antibiotic was investigated. Structural characteristics of synthesized chitosan were determined by Scanning Electron Microscopy (SEM), and X-Ray Diffraction (XRD). Also, the isotherm, thermodynamics, and kinetics of the adsorption process were studied. The results of this study showed that the maximum adsorption capacity of chitosan in optimum condition (pH=7, adsorbent dose: 0.25 g/L, the concentration of antibiotics: 70 mg/L, and contact time: 10 min) was 101.44 mg/g. SEM image showed that the size of chitosan was ranging from 700 nm to 5 microns. The results of XRD analysis showed the successful synthesis of chitosan. Experimental data indicate that the results are consistent with the Langmuir isotherm model and that the adsorption process was followed by a pseudo-second-order model. According to the results of thermodynamic studies, the standard entropy variations (∆S) were 20.68 (J/mol k) and standard enthalpy changes (∆H) were 5.69 kJ/mol and standard Gibbs free energy (∆G) values were negative and respectively indicates that adsorption process of penicillin G by chitosan is spontaneous and endothermic.Keywords: Chitosan, Antibiotics, Penicillin G, Adsorption
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Fluoride, a non-essential element, can enter water resources through several natural processes and human activities. The benefits and risks of fluoride depend on the concentration of this anion on drinking waters. In the present study, the performances of graphene and graphene oxide nanoparticles were investigated for the removal of fluoride from aqueous solution. In the present research, effects of pH, contact time, fluoride initial concentration, adsorbents dosage, as well as temperature in performance of graphene and graphene oxide nanoparticles in removal of fluoride from aqueous solution were examined. Also, isotherms and thermodynamics of the adsorption process were evaluated. For both adsorbents, the maximum adsorption capacities observed during the first 15 minutes at pH=3 and an initial fluoride concentration of 10 mg/L. The results also showed that adsorption of fluoride by graphene and graphene oxide fitted well with Freundlich and Langmuir isotherms, respectively. Furthermore, temperature increase resulted in the adsorption capacity decrease, indicating an exothermic adsorption reaction. According to the results of this research, graphene nanoparticles have higher adsorption capacity of fluoride than graphene oxide nanoparticles.Keywords: nanoparticles, Graphene, Graphene oxide, fluoride
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زمینه و هدف
افزودن نمک به مواد غذایی از جمله نان در کنار بهبود طعم آن می تواند مشکلاتی از جمله بالابردن فشار خون را ایجاد نماید؛ بنابراین با توجه به اهمیت وجود نمک در نان، هدف از این مطالعه بررسی میزان نمک نان در نانوایی های استان خراسان جنوبی در سال 97-1393 بود.
روش تحقیقاین مطالعه توصیفی- تحلیلی و گذشته نگر با روش نمونه گیری تصادفی بر روی نانوایی های سطح استان خراسان جنوبی در بازه زمانی سال های 97-1393 انجام گردید. اندازه گیری میزان نمک، مطابق استانداردهای موسسه استاندارد و تحقیقات صنعتی ایران انجام شد. از آزمون های آنالیز واریانس و تعقیبی توکی برای تجزیه و تحلیل داده ها استفاده گردید.
یافته هاتعداد 2577 قرص نان طی سال های 1397-1393 به آزمایشگاه مواد غذایی استان خراسان جنوبی ارسال گردید که میانگین کلی میزان نمک در نان لواش برابر با 0/57±1/63 گرم، تافتون 0/53±1/51گرم و در نان سنگگ برابر با 0/56±1/42 گرم بود. نتایج میانگین میزان نمک در سال های مختلف با یکدیگر اختلاف معناداری داشتند (p<0/001).
نتیجه گیریمقدار نمک مصرفی از نظر تغییرات میانگین مصرف نان در سال 1395، بیشترین میزان بوده است که به نظر می رسد علت آن عدم آگاهی نانوایان از تغییر استاندارد نمک در آن سال باشد؛ در نتیجه اتخاذ برنامه های پیشگیرانه و نظارتی معاونت غذا و دارو می تواند در این زمینه رهگشا باشد.
کلید واژگان: نانوایی، نان، نمک، خراسان جنوبیBackground and AimAdding salt to foods including bread along with improving its taste can cause problems such as high blood pressure; therefore, considering the importance of the presence of salt in bread, the purpose of this study was to investigate the amount of bread salt in bakeries in South Khorasan province in 2014-2018.
Materials and MethodsThis descriptive-analytical and retrospective study was performed by random sampling method on bakeries in South Khorasan province in the period of 2014-2018. The measurement of the salt level was done according to the standards of the Iranian Institute of Standards and Industrial Research. The data were analyzed by using variance analysis tests and Tukey's post-hoc test.
Results2577 loaves of bread were sent to the food laboratory of South Khorasan province during the years 2014-2018, which is the total average amount of salt In Lavash bread, it was equal to 1.63 ± 0.57 g, Taftoon was 1.51 ± 0.53 g, and in Sangag bread, it was 1.42 ± 0.56 g. The mean results of salt levels in different years had significantly different (p <0.001).
ConclusionThe amount of salt consumed was the highest in terms of changes in the average consumption of bread in 2016, which seems to be due to the lack of awareness of bakers about changing the standard of salt in that year. In this regard, the adoption of preventive and regulatory programs by the Food and Drug Administration can be a guide.
Keywords: Bakery, Bread, Salt, South Khorasan -
Untreated wastewater disposal containing synthetic dyes produces serious problems in the environment. Industrial wastewater containing dye requires treatment by a suitable process before discharging into the environment. The present study has been performed as a batch experimental study. Nanochitosan was synthesized from the Persian Gulf shrimp shell. The effect of the various parameters including pH, initial concentration of the RB29 dye, the equation contact time, and the adsorbent dosage as well as isotherm, thermodynamic and kinetic of the adsorption process were evaluated. The results of this study demonstrated that the maximum adsorption capacity of the nano chitosan, which occurred in pH=4, adsorbent dosage of 0.2 g/L, the concentration of 50 mg/L of RB29 dye and during 90 minutes, was 113.22 mg/g. Temkin and Dubinin-Radushkeish isotherms and pseudo-second-order kinetic equations have shown better results for describing the adsorption process. The entropic changes (ΔS°) and enthalpy changes (ΔH°) were 36.65J/mole K and 6.43 kJ/mole respectively. Also, the Gibbs free energy (ΔG) was negative. Therefore nano chitosan can be used as a suitable low-cost adsorbent for the removal of RB29 dye from aqueous solutionsKeywords: RB29 dye, nanochitosan, Adsorption, Isotherm, thermodynamic, Kinetics
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Background & Aims of the Study:
Many people use natural springs for many years to provide therapeutic, recreational, and in some cases, drinking water. The investigation of physicochemical properties and promotion of its indices in hot springs are very important for maintaining the health and well-being of individuals. The present study aimed to investigate some physicochemical properties of hot springs in South Khorasan, Iran, and compare them with the standards in 2018.
Materials and MethodsIn order to assess the physicochemical quality of hot springs in South Khorasan, temperature, pH, electrical conductivity (EC), alkalinity, and total hardness parameters were measured and analyzed using standard methods. Data analysis was performed using Excel software (version 2010).
ResultsBased on the obtained results, the highest temperature and EC were observed in Dig-e Rostam hot spring with 54.3°C and Ferdowshotspringwith10.43 μs/cm, respectively. Furthermore, the highest pH, alkalinity, and total hardness were obtained in Qaen hot spring with 7.87, Sarbisheh hot spring with 2018 mg/L CaCo3, and Ferdows hot spring with 1204 mg/L CaCo3, respectively.
ConclusionBased on the results obtained from the review of the physicochemical quality of the hot springs in the southern Khorasan, most of the measured parameters of the springs were not within the standard range.
Keywords: physicochemical quality, Hot water springs, South Khorasan -
The activity of different transitional metals over modified H-ZSM-5 catalysts for methane conversion to aromatics was compared. The first group of catalysts was Mo-impregnated H-ZSM-5 zeolites with 1, 3 and 6 wt% of Mo. The second group was M(3 wt%)- impregnated H-ZSM-5 (M: Ag, Cd, Cr, Mo, Zn and Mn). The catalytic activity of the first group was investigated at 600, 700 and 800 °C and gas hourly space velocity (GHSV) of 1500, 2250, 3600 [ml.g-1.h-1]. Likewise, the second group of catalysts was examined at 700°C and GHSV of 2250 [ml.g-1.h-1]. The catalyst samples were appropriately characterized by XRD, BET and SEM techniques. The effect of loaded transitional metals on the methane conversion was sorted on the basis of benzene yield as following: 3%wt Mo> 3%wt Zn> 3%wt Mn> 3%wt Ag> 3%wt Cd > 3%wt Cr. The highest methane conversion was 11.13% obtained over the Mo(3 wt%)-impregnated HZSM-5 catalyst.Keywords: Natural gas, Dehydro-aromatization, HZSM-5 metal-modified catalyst, Nonoxidative-conversion
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در اواسط سال 1391 با اعمال تحریم ها و کاهش ارز حاصل از صادرات نفت، تنظیم بازار ارز توسط دولت غیرممکن و نرخ ارز مبادله ای جایگزین نرخ ارز مرجع گردید و در پی آن معادل ریالی تسهیلات ارزی شرکت ها چند برابر شد و این تفاوت می بایست به زیان تسعیر ارز دوره منظور می گردید، در این راستا سازمان حسابرسی در مرداد ماه 1392 با اصلاح استاندارد حسابداری 16 با لحاظ شرایطی، مجوز انتقال زیان تسعیر ارز تسهیلات مالی ارزی را به بهای تمام شده دارایی های ایجاد شده صادر نمود. در تحقیق حاضر بررسی شده است که سرمایه گذاران، با اعمال استاندارد اصلاح شده، افزایش گزارشگری سود این شرکت ها را به عنوان یک خبر خوب در بازار تلقی نموده یا اینکه این امر را هموارسازی سود و موجب کمبود نقدینگی آتی این شرکت ها پیش بینی کرده و آن را علامت مثبتی نمی دانند. بدین منظور با مقایسه میانگین درصد تغییرات ارزش و حجم مبادلات سهام شرکت های نمونه قبل و پس از اصلاح استاندارد حسابداری شماره 16 و اجرای آزمون ناپارامتری رتبه علامت ویلکاکسون مشخص گردید: در بازه های زمانی 21 و30 روزه ارزش مبادلات سهام بعد از اصلاح استاندارد " آثار تغییر در نرخ ارز" نسبت به قبل کاهش یافته است و در بازه های زمانی 21، 30 و 50 روزه حجم مبادلات سهام بعد از اصلاح استاندارد " آثار تغییر در نرخ ارز" نسبت به قبل کاهش یافته است.کلید واژگان: ارزش مبادلات سهام، رفتار سرمایه گذاران، آثار تغییر در استاندارد، کیفیت حجم مبادلات سهامsanctions and reduced foreign exchange earnings from oil exports, government regulation of the currency market and exchange rates exchange got impossible and alternative exchange rate was replaced with reference exchange rate, Followed by, Rials Equivalent of corporate foreign exchange facilities Multi-fold increased and This difference should be accounted in the foreign currency loss for that period. In this regard, the Audit Organization in August 1392 by amending the Accounting Standard no.16 with the terms of position gave the license of transferring foreign losses in the foreign currency financing facilities granted to the cost of the assets created. This study investigated that investors, by applying the amended standard, consider reporting increased profits are regarded as good news in the market or consider it as income smoothing that predicting firms Lack of future cash and is not a positive signal. Therefore, the mean percentage change in stock value and volume of firms in the sample before and after the amendment of the accounting standard No. 16 and performing Non-parametric Wilcoxon rank test, was found: At intervals of 21 and 30 days, the value of stock transactions after the modified standard "The effects of changes in exchange rates" has decreased than before and at intervals of 21, 30 and 50 days, the volume of stock transactions after the modified standard "The effects of changes in exchange rates" has decreased than beforeKeywords: The Volume of Stock Exchanges, Tthe Value of the Stock Exchanges, Investors' Behavior, The Effects of Changes in the Standard.
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BackgroundHumic acid is a trihalomethane component in water supplies, causing various health disorders in humans.ObjectivesThis study was performed to examine humic acid adsorption on saturated activated carbon and to evaluate adsorbent regeneration through ultrasonic processes.MethodsIn the present study, effects of various parameters, including initial concentration of humic acid, pH, contact time, adsorbent dose, and temperature, on the adsorption stage were investigated. Also, effects of different parameters, such as regeneration time, pH, and number of saturation-regeneration cycles, were studied in the regeneration stage.ResultsThe highest percentage of humic acid removal was reported at pH of three and initial humic acid concentration of 10 mg/L. The highest adsorption capacity of activated carbon was 29.7 mg/g at adsorbent dosage of 0.1 g/L and contact time of 10 minutes. The results of thermodynamic experiments showed that removal of humic acid by saturated activated carbon was endothermic. Also, maximum regeneration occurred at pH of 11 and contact time of 60 minutes. Finally, the adsorption capacity of saturated activated carbon changed from 42.94 to 42.14 mg/g after five cycles of saturation and regeneration.ConclusionsThe results of this study showed that activated carbon is an effective adsorbent in the removal of humic acid from water. Also, the ultrasonic process is effective in regeneration of activated carbon, saturated with humic acid.Keywords: Adsorption, Humic Acid, Ultrasonic Regeneration, Activated Carbon
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BackgroundNowadays, different methods are applied for the removal of heavy metals from the aqueous resources that the adsorption process is one of them. The chromium VI is one of the most prevalent contaminants which create serious difficulties; so, it should be removed from the contaminated waters by an effective method before being leaved into the environment. The present research investigated the use of dried powder of activated sludge of Kavirtire wastewater treatment plant as bio sorbent for removal of chromium (VI).MethodsIn the present experimental study, the effects of pH, adsorbent dose, primary concentration of metal and contact time on the removal of chromium (VI) from the aqueous solutions were studied. Then, the equations of isotherm and adsorption kinetic were specified based on the optimal conditions. The absorbent features were analyzed by SEM and EDX techniques.ResultsThe maximum efficiency of the removal of chromium (VI) at pH 2, optimal dose of 5 g/L, contact time of 60 min and with primary concentration of 15 mg/L was reported 99.83 percent. The study of relation of the isotherm and kinetic in the reaction revealed that the process of adsorptions of chromium follows the Freundlich model (R2=0.90) and the pseudo- second order kinetic model (R2= 1), respectively.ConclusionsThe dried powder of activated sludge can be applied as a proper adsorbent for the removal of Chromium VI from the aqueous resources.Keywords: Bio, sorbent, Wastewater, Adsorption, Chromium(VI), Isotherm
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Iranian Journal of Chemistry and Chemical Engineering, Volume:36 Issue: 6, Novr-Dec 2017, PP 127 -137Dyeing wastewaters are one of the most common pollutants that cause many problems for public health and environment due to dermatitis and skin rashes, cancer production, mutagenesis, etc. Thus, treatment of these wastewaters is necessary. The purpose of this study was to investigate the efficiency of montmorillonite nanoparticles as an adsorbent in adsorption process of Reactive Yellow 15 (RY15) and Reactive Yellow 42 (RY42) dyes from aqueous solutions. In this study, montmorillonite nanoparticles were used to remove RY15 and RY42 dyes. The effect of different variables such as pH, contact time, dye concentration and adsorbent dosage was studied. Finally, the effect of process temperature and thermodynamic was studied. Also, pseudo-first and second orders of kinetics were studied. The results showed that 3 is the best pH for the removal of both dyes. As contact time increases to 15 minutes, adsorption capacity increases and then reaches an approximately constant value. Adsorption capacity was also increased with increased dye concentration. By changing the adsorbent dosage from 0.2 to 0.6 g/L, adsorption capacity for RY15 and RY42 was reduced from 142and 166 to 63 and 59 mg/g, respectively. The results also showed that both dyes had the highest correlation with pseudo-second-order kinetics. The results of analyzing the process thermodynamics and temperature showed that values of DH, DS and DG are negative for both dyes.Keywords: Montmorillonite nanoparticles, Adsorption, Reactive Yellow dye, Textile, Wastewater, Kinetic, Thermodynamic
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This study was aimed to investigate the amount of reactive blue 29 (RB29) dye removal from aqueous solution by Chitosan extracted from Persian Gulf shrimp shell. The effect of parameters such as pH, the concentration of reactive blue 29 dye, contact time, and adsorbent dosage in dye removal was studied. Isotherm, Thermodynamics, and kinetics of adsorption process were also investigated. The results of this study showed that the optimum condition of the adsorption process occurred in 50mg/L of RB29 dye concentration, pH=4, contact time of 90 minutes and adsorbent dosage of 0.2 g/L. The maximum adsorption capacity in optimum condition was estimated to 87.74 mg/g. Lab data displayed that the results were in compliance with Langmuir isotherm. According to the results of thermodynamic studies, standard entropy changes (ΔS°) was 66.67 J/mol K and standard enthalpy changes (ΔH°) was 19158.3 kJ/mol. Also, the standard Gibbs free energy (ΔG°) was negative and kinetics of adsorption process follows the pseudo-second-order modelKeywords: Reactive blue29 dye, Chitosan, Isotherm, Thermodynamics, kinetics
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Background & Aims of the Study: Malaria is an infectious disease by fever, chills and anemia; and splenomegaly genus Plasmodium parasite is the agent of it. One of the easiest and least expensive methods for preventionof this disease is removing the vector that usually has been done by insecticides and chemical pesticides, but now days due to the harmful effects of toxic chemicals, it is currently trying to use organic toxic and plant compounds in order to combat the pests. So, in this study Hyoscyamus niger was used in order to destroy the larvae of this insect and positive results were compared these plants together.Materials And MethodsHyoscyamus niger was collected and dried to extract by methanol in a rotary evaporator. Mosquito larvae were collected from stagnant water pits and ponds around the Birjand city, South Khorasan of Iran in order to apply the relevant tests identity and isolated Anopheles spp mosquito larvae.ResultsHyoscyamus niger positive effect was destroying on the Anopheles spp larvae and between obtained results, the most powerful extract for destroying the mosquitoes Anopheles spp larvae was the flower extract of henbane (LC50=0.07) and the weakest extract was the extract of the root of henbane (LC50=0.78).ConclusionAccording to the results it is recommended the flower extract of henbane as a toxic, organic and natural compound to fight the larvae of Anopheles spp mosquito larvae which used in the other parts of these plants more stronger and more effective.Keywords: Malaria, Anopheles spp, larvae, Hyoscyamus niger L, Henbane, Iran
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BackgroundAdsorption isotherms describe the relationship between the equilibrium concentration of the adsorbed matter in the solution and the amount of adsorbed matter on the surface of the adsorbent.ObjectivesThe main objective of the present research was to investigate different adsorption isotherms for describing adsorption of humic acid by nanoclay.MethodsIn this study, Langmuir, Freundlich, BET, Temkin and Dubinin Radushkevich isotherms, for describing the behavior of humic acid adsorption by bentonite and montmorillonite nanoparticles, were examined.ResultsThe results showed that due to the regression coefficient (R2), humic acid adsorption on bentonite and montmorillonite nanoparticles has greater compliance with Dubinin Radushkevich isotherms. The value of E or average energy of adsorption for humic acid by bentonite and montmorillonite nanoparticles was 0.17 and 0.15 kJ mol-1, respectively, which specifies that the type of adsorption of humic acid on both nanoparticles was physisorption. The qmax value obtained from the Dubinin-Radushkevich isotherms, for bentonite and montmorillonite nanoparticles were 27.78 and 28.70 mg/g, respectively.ConclusionsAccording to the results of this study, bentonite and montmorillonite nanoparticles have a great potential for the removal of humic acid from aqueous solutions.Keywords: Nanoparticles, Bentonite, Montmorillonite, Isotherms, Humic Acid
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زمینه و هدفمواد هیومیکی از جمله مواد پلی الکترولیتی آلی طبیعی هستند که بیشترین قسمت کربن آلی محلول موجود در محیط های آبی را تشکیل می دهند. واکنش بین ترکیبات هیومیکی و کلر منجر به تشکیل محصولات جانبی گندزدایی می شود که سمی، سرطان زا و جهش زا هستند. هدف از این مطالعه بررسی ایزوترم، سینتیک و ترمودینامیک فرآیند حذف اسید هیومیک توسط نانو کیتوزان از محیط های آبی بود.
روش تحقیق: این مطالعه کاربردی از نوع تجربی بود که به صورت سیستم ناپیوسته انجام شد. در این مطالعه، اثر پارامترهای مختلفی از جمله: pH، غلظت اسید هیومیک، زمان تماس، میزان جرم جاذب، ایزوترم، ترمودینامیک و سینتیک فرآیند جذب اسید هیومیک بررسی شد. غلظت اسید هیومیک با استفاده از روش اسپکتروفتومتری در طول موج 254 نانومتر تعیین گردید.یافته هانتایج این مطالعه نشان داد که حداکثر ظرفیت جذب نانوکیتوزان که در غلظت l mg/50 و زمان تماس 90 دقیقه رخ داد، برابر mg/g3/52 است. همچنین حداکثر میزان جذب در 4pH= و در دوز جاذب g02/0 مشاهده شد. داده های آزمایشگاهی نشان دهنده تطابق نتایج با مدل ایزوترم لانگمویر بود. مطابق نتایج مطالعات ترمودینامیک تغییرات آنتروپی ΔS)) برابر
J/mol k24/2-، تغییرات آنتالپی (ΔH) برابر kJ/mol870 و مقدار انرژی آزاد گیبس ((Δ G منفی بود که نشان دهنده خودبه خودی و گرماگیر بودن فرآیند جذب می باشد. سینتیک فرآیند جذب سطحی از مدل شبه درجه دو تبعیت می کند.نتیجه گیریبا توجه به نتایج حاصل از این مطالعه، می توان نانوکیتوزان را جاذب مناسبی برای حذف اسید هیومیک از محلول های آبی پیشنهاد کرد.کلید واژگان: اسید هیومیک، نانوکیتوزان، جذب سطحی، ایزوترم، ترمودینامیک، سینتیکBackground And AimHumic substances include natural organic polyelectrolyte materials that formed most of the dissolved organic carbon in aquatic environments. Reaction between humic substances and chlorine leading to formation of disinfection byproducts (DBPs) those are toxic, carcinogenic and mutagenic. The aim of this study was investigation of isotherms, kinetics and thermodynamics of humic acid removal process by nano chitosan from aquatic environment.Materials And MethodsThis practical research was an experimental study that performed in a batch system. The effect of various parameters such as pH, humic acid concentration, contact time, adsorbent dosage, isotherms, thermodynamics and Kinetics of humic acid adsorption process were investigated. Humic acid concentration measured using spectrophotometer at wave length of 254 nm.ResultsThe results of this research showed that maximum adsorption capacity of nanochitosan that fall out in concentration of 50 mg/l and contact time of 90 minutes was 52.34 mg/g. Also, the maximum adsorption was observed in pH = 4 and adsorbent dosage 0.02 g. Laboratory data show that adsorption of humic acid by nanochitosan follow the Langmuir isotherm model. According to result of thermodynamic study, entropy changes (ΔS) was equal to 2.24 J/mol°k, enthalpy changes (ΔH) was equal to 870 kJ/mol and Gibbs free energy (ΔG) was negative that represent the adsorption process is spontaneous and endothermic. The kinetics of adsorption has a good compliant with pseudo second order model.ConclusionRegarding to results of this study, nano chitosan can be suggested as a good adsorbent for the removal of humic acids from aqueous solutions.Keywords: Humic acid, Nano chitosan, Adsorption, Isotherms, Thermodynamics, Kinetics -
Copper and hexavalent chromium are heavy metals that are harmful to human health. Natural adsorbent chitosan, due to its considerable properties such as the presence of functional groups of NH2 and -OH, non-toxicity, low cost, and biocompatibility, has gained much attention in pollutant removal. Therefore, in the present study, adsorption of chromium (VI) and copper (II) ions was conducted in a batch system using magnetic chitosan/Fe-Zr nanoparticles. In addition, the effect of different variables such as contact time, pH, adsorbent dose, initial concentration of heavy metals, and temperature were investigated. The results of the present study indicated that the highest efficiency in removal of chromium (VI) and copper (II) in pH of 4 were 99.52% and 97.72%, respectively. Moreover, adding 0.4 g of the composite at concentration of 5 mg/l can result in up to 97.43% removal of copper (II) and adding 1 g of this composite at the same concentration can result in more than 91% removal of chromium (VI). In addition, it was concluded that increasing the density of the heavy metals did not have a remarkable effect on the removal efficiency. The equilibrium related to adsorbent capacity and the amounts of nanoparticles were obtained using the plots of Langmuir and Freundlich adsorption isotherms for chromium (VI) and copper (II), respectively. The studied adsorbent had a high level of efficiency in the removal of heavy metals from aqueous solutions.Keywords: Magnetic Chitosan, Adsorption, Chromium, Copper
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