gold
در نشریات گروه مهندسی معدن-
مجله محیط و معدن، سال چهاردهم شماره 4 (Autumn 2023)، صص 1239 -1260
This study reports the application of remote sensing data and knowledge-driven GIS modeling to provide favorability maps for gold and copper mineralized areas. The South Gabal Um Monqul (SGUM) and the Gabal Al Kharaza (GKZ) prospects located in the northern Eastern Desert of Egypt are the targets for the present study. Four thematic layers (lithology maps, old trenches buffer analysis, lineament density maps, and alteration zone maps) were prepared and used as inputs for a weighted overlay GIS model. Combined results from false color composite images, particularly the RGB parameters (PC2, PC1, and PC3) and the RGB parameters (MNF1, MNF2, and MNF3) classified the host rocks in both prospects. PCA-based extraction of lineaments was considered using line algorithm of PCI Geomatica. QuickBird band math (G+B), (R+G), and (G-B) for RGB was successful in delineating ancient workings within the mineralized zones. Old trenches layers were buffered to 20 m wide bands extending in all directions. Landsat-8 band ratios imagery (6/5 * 4/5, 6/7, and 6/2) in red, green, and blue (RGB) is potent in defining alteration zones that host gold and copper mineralizations. Acceptable scores of 30%, 30%, 20%, and 20% were assigned for the alteration zone maps, ancient workings buffer analysis, lithology maps and lineament density maps, respectively. Two favorability maps for mineralizations were generated for the SGUM and GKZ prospects. Validation of these maps and their potential application to detect new mineralization sites in the northern Eastern Desert were discussed.
Keywords: remote sensing, GIS analysis, gold, copper mineralization, Favorability maps, knowledge-driven method -
This study presents an analysis of aeromagnetic and aero-radiometric data from the Chitipa area in northern Malawi to delineate structures, hydrothermal alteration areas, and gold mineral potential zones, as well as to identify prospective regions for further mineral exploration. Airborne geophysical data, specifically aeromagnetic and aero-radiometric data, were utilized. We applied several enhancements and filters to the geophysical data, including reduction to the pole, the first vertical derivatives, analytical signal, tilt angle derivative enhancements, Centre for Exploration Targeting (CET) grid analysis, Euler deconvolution, and radiometric data ratios. The results of the analysis provided detailed information on the subsurface geology and indicate that the area is characterized by faulting and shearing with structures predominantly trending in a northwest direction, and minor trends in the northeast-southwest, east-west, and north-south directions. Zones with hydrothermal alteration were found to coincide with structural associations in the NW part of the study area, indicating that the structures served as channel ways for migrating hydrothermal fluids that reacted with the rock formation, resulting in alteration. The northwest area is a promising mineralization zone, and further exploration should focus on this area.Keywords: Gold, base metal, Mineralisation, Chitipa, Mineral exploration, airborne geophysics
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This paper elucidates a new idea and concept for exploration of the gold ore deposits. The cyanidation method is traditionally used for gold extraction. However, this method is laborious, time-consuming, costly, and depends upon the availability of the processing units. In this work, an attempt is made in order to update the gold exploration method by the Monte Carlo-based simulation. An excellent approach always requires a high quality of the datasets for a good model. A total of 48 incomplete datasets are collected from the Shoghore district, Chitral area of Khyber, Pakhtunkhwa, Pakistan. The cyanidation leaching test is carried out in order to measure the percentage of the gold ore deposits. In this work, the mean, median, mode, and successive iteration substitute methods are employed in such a way that they can compute the datasets with missing attributes. The multiple regression analysis is used to find a correlation between the potential of hydrogen ion concentration (pH), solid content (in %), NaCN concentration (in ppm), leaching time (in Hr), particle size (in µm), and measured percentage of gold recovery (in %). Moreover, the normal Archimedes and exponential distributions are employed in order to forecast the uncertainty in the measured gold ore deposits. The performance of the model reveals that the Monte Carlo approach is more authentic for the probability estimation of gold ore recovery. The sensitivity analysis reveals that pH is the most influential parameter in the estimation of the gold ore deposits. This stochastic approach can be considered as a foundation to foretell the probabilistic exploration of the new gold deposits.
Keywords: Cyanidation process, Exploration, Gold, Monte Carlo Simulation, Sensitivity Analysis -
Oxidation of sulfide-containing ores is the main cause of Acid Mine Drainage (AMD), which is an environmental problem associated with both the abandoned and active mines. Iron-bearing sulfide minerals can be oxidized and form mine waters with high sulfate content, low pH, high electrical conductivity, high redox potential, and high concentrations of iron, aluminum, and other heavy metals. In the process of AMD, precipitation of poorly crystalized oxy-hydroxides of iron with a large active surface can occur. On the surface of iron oxy-hydroxide, the precipitated particulate matter, anions, and cations (metals) could be adsorbed. Mine waters can contain a certain amount of precious metals that can also be adsorbed onto an iron particulate matter surface, which is investigated in this research work. In this work, the samples of iron oxy-hydroxide particulate matter at abandoned gold mine waste in Bakovići (Central Bosnia and Herzegovina) are used. Several parameters including pH, water content, particle size distribution, sulfate content, electrical conductivity, redox potential, and amounts of gold, silver, and iron are measured on the selected mine waste samples. The results obtained indicate that significant amounts of gold (average: 6.8 mg/kg) and silver (average: 7.13 mg/kg) are present in the iron precipitate. Adsorption of precious metals onto the iron oxy-hydroxide surface is strongly pH-dependent. At a very low pH value, desorption of precious metals is favorite. Thus, precious metals are only partially adsorbed onto the iron oxy-hydroxide surface.
Keywords: AMD, mine, Iron, Gold, silver -
تحلیل رگرسیونی به عنوان بخش مهمی از اکتشاف ذخایر طلا با داده های ژئوشیمیایی با ماهیت ترکیبی سر و کار دارد. در داده های ترکیبی، متغیرهای عیاری بخشی از کل بوده و اطلاعات مفید در آنها در قالب نسبت متغیرها وجود دارد. محدود بودن داده ها در بازه صفر تا 100 درصد باعث ایجاد همبستگی تحمیلی و کوواریانس دروغین شده و این موضوع، تحلیل های آماری مرسوم را با اشتباه و عدم قطعیت همراه خواهد کرد. این موضوع برای داده های ژئوشیمیایی که مجموع آنها به 100 درصد نمی رسد نیز ثابت شده است. در این پژوهش تحلیل رگرسیونی عیار طلا در یک رخداد معدنی طلا در شمال غربی ایران با دو رویکرد سنتی (رگرسیون غیرخطی چند متغیره داده های خام) و ترکیبی (رگرسیون غیرخطی چند متغیره بالانس های به دست آمده از تبدیل نسبت لگاریتمی ایزومتریک (ilr)) مورد توجه قرار گرفته است. هدف از این کار مقایسه توانایی دو رویکرد در برآورد دقیق عیار طلا است. ضریب همبستگی مقادیر واقعی و تخمینی برای رویکرد سنتی 74/0 و برای رویکرد ترکیبی 84/0 و نرخ طبقه بندی صحیح (CCR) به عنوان مثال در عیار ppb40 به ترتیب 688/0 و 875/0 است. به علاوه، تابع توزیع مقادیر تخمینی با رویکرد ترکیبی بیش از رویکرد سنتی به تابع توزیع داده های واقعی شبیه است. همچنین، رویکرد سنتی در یک نمونه، عیار طلا را کم تر از صفر تخمین زده است. این تناقض آشکار نشانه ای از نامناسب بودن روش های سنتی ریاضی برای کار با داده هایی با سیستم بسته است. به علاوه، رویکرد ترکیبی در برآورد چارک های اول و سوم که مقادیر حیاتی تری در جدایش داده های آنومال هستند، تخمین های دقیق تری ارائه نموده است. مجموع این موارد دلالت بر این دارند که به منظور یک تحلیل آماری دقیق و قابل اعتماد، باید ماهیت ترکیبی داده های ژئوشیمیایی مورد توجه واقع شده و داده ها با روش نسبت لگاریتمی مناسب تحلیل شوند.کلید واژگان: داده ترکیبی، تبدیل نسبت لگاریتمی ایزومتریک ilr، رگرسیون چند متغیره، فاصله ماهالانوبیس، طلا، قره چرJournal of Aalytical and Numerical Methods in Mining Engineering, Volume:9 Issue: 18, 2019, PP 1 -16SummaryWhen a geochemical sample is analyzed, grades are reported as strictly positive and constrained values, which are a form of compositional data (CoDa). It is proven that spurious correlations of closed data can affect the conventional statistical analysis such as regression modeling. The problem is that one cannot say how much of the uncertainty of the model is due to spurious covariance and correlations. Thus, it is wiser to choose the safe side and consider the compositional nature of the data using proper logratio approach. In this study, we assessed the regression analysis of gold grade in a gold occurrence located in the NW Iran. Compositional and noncompositional approaches were followed and the consequent results were compared to understand the impact of neglecting the compositional nature of data on gold grade regression analysis. Isometric logratio (ilr) balances were calculated and used to perform the compositional approach.
Comparison of the two approaches was carried out based on Correct Classification Rate (CCR) of the estimated values and the correlation coefficient of the estimated and real gold grades (R2). Additionally, the resemblance between the distribution of the estimated and real data were compared. R2 values for compositional and noncompositional approaches are 0.84 and 0.74 respectively, and CCR values at 40 ppb cut-off are 0.875 and 0.688 for the same set. On the other side, the distribution of estimated grades by compositional approach is closer to the real gold grades. It is notable that the noncompositional approach has estimated a negative grade, which is an evident inconsistency. Although the noncompositional approach is returning the exact value of the average, the compositional approach is more accurate at the first and the third quartiles, which are more critical.
All above-mentioned results approve that CoDa analysis of lithogeochemical data is essential. It is concluded that neglecting the compositional nature of data will compromise the reliability of the regression models. Thus, to stay away from the falsification, it is highly recommended to perform the proper logratio approach in multivariate statistical studies of geochemical data.IntroductionAlmost all geochemical data are reported as constrained and strictly positive grades and concentrations. They count as a form of compositional data. Statistical analysis of such data, in the raw form, is exposed to inconsistency and can result unrealistic models. Logratio approach is an adequate way to treat the problem.Methodology and ApproachesMultivariate regression analysis of the raw and logratio transformed data was performed and the results were compared. Isometric logratio (ilr) transform was executed to calculate unconstrained balances for the compositional approach.Results and ConclusionsThe compositional approach outperforms the noncompositional approach in terms of Correct Classification Rate (CCR) and R2 (correlation coefficient of estimated and real data). In addition, the noncompositional approach inconsistently estimated a negative grade and is less accurate in the first and the third quartiles of the population. It is concluded that the compositional data analysis is essential when we are working with multivariate geochemical data.Keywords: Compositional data (CoDa), Isometric logratio transform (ilr), Multivariate regression analysis, Mahalanobis distance, Gold, Qareh Char -
برگه یکصدهزارم ژئوشیمیایی طرق، واقع در استان اصفهان است. این ناحیه چینه شناسی سنگهای پرکامبرین تا کواترنر را دارد و در زون ایران مرکزی واقع شده است. با توجه به وجود نشانه هایی از کانیسازی طلا در این منطقه، شناسایی مناطق با اهمیت معدنی در این منطقه لازم است. بنا به همین امر، یافتن اطلاعاتی در مورد ارتباط و رفتارسنجی عناصر طلا، آرسنیک و آنتیموان نسبت به یکدیگر در این منطقه، برای پیدایش و تعیین وسعت هاله های ژئوشیمیایی، تعیین امیدبخش بودن ناحیه و تخمین عیار ضرورت مییابد. بنا براین در پژوهش حاضر برای رفتارسنجی عناصر نام برده، از روش مشهور و مفید کا- میانگین استفاده می شود که روش خوشهبندی است که بر کمینه کردن مجموع فواصل اقلیدسی هر یک از نمونه ها از مرکز دسته هایی که به آن تخصیص می یابد، استوار است. در این تحقیق از تابع کیفیت خوشهبندی و میزان مطلوبیت نمونه در خوشه مورد نظر ((i)S) برای تشخیص تعداد خوشه بهینه استفاده و در انتها با در نظرگرفتن مراکز خوشه ها و نتایج حاصل، معادلاتی برای پیشبینی مقدار عنصر طلا بر حسب چهار پارامتر عیار آرسنیک، عیار آنتیموان، طول و عرض نقاط نمونهبرداری ارایه شد که ضریب همبستگی اعتبارسنجی آن برابر با 72 درصد گزارش شده است. نتایج حاصل نشان دهنده برتری رفتارسنجی عناصر با روش یاد شده نسبت به ضرایب همبستگی از سایر روش های مرسوم است.کلید واژگان: طلا، طرق، روش خوشه بندی کا، میانگین، تخمین عیار عناصر، K، meansThe studied area could be found in Tarq 1:100000 Geochemicalmap. Initial geochemical investigation is done by Iran Geological Survey and Mineral Exploration (IGS) using stream sediments analysis method. This district mainly is covered by Precambrian to Quaternary Rocks. The geochemistry of the gold mineralization seems to be very important with regard to the sign of gold mineralization. Based on this aim, it is important to find the relationship of geochemical behavior of Au, As and Sb within the reported geochemical halo to determine both promising areas and gold estimated grade. To achieve this goal, K-means which is a powerful method has been applied. K-means is a clustering method based on minimizing sum of Euclidean distances of each sample from their own group centers. Here, the clustering quality function (S(i)) and the desirability of the cluster are used to find the optimized number of clusters. Finally, by taking into account the cluster centers and the results concerned, equations were presented for the prediction of the amount of the gold element in terms of four parameters: arsenic, antimony, X and Y associated to the sampling points. Also shown are the correlation coefficient of its validation equal to 72. The superiority of the results of the behavioral measurement of the elements related to this method were compared to the correl.Keywords: Gold, K, means Clustering, Grade estimation, Tarq, Iran
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در حال حاضر روش فرآوری طلای موته، لیچینگ سیانیدی است که بار ورودی زیادی به این بخش وارد می شود که شامل باطله های همراه طلا است و هزینه های اقتصادی زیادی را منجر می شود. هدف از این تحقیق بررسی امکان حذف باطله های همراه طلا و پرعیارسازی بار ورودی به مرحله لیچینگ سیانیدی، به وسیله یکی از روش های پرعیارسازی مانند فلوتاسیون یا ثقلی است که در این صورت، باعث کاهش بار ورودی به مرحله لیچینگ سیانیدی و اقتصادی تر شدن فرآیند خواهد شد. از آنجایی که انتخاب روش فرآوری مناسب و اقتصادی برای استحصال طلا، مستلزم شناسایی دقیق کانی های حاوی طلا در کانسنگ است، در این پروژه برای شناسایی کانی های حاوی طلا و بررسی نحوه درگیری طلا در نمونه موجود از کانسنگ طلای موته، از روش لیچینگ تشخیصی استفاده شد. نتایج دو آنالیز حرارتی، عیار طلا در نمونه موجود را ppm85/0 و ppm86/0 گزارش کرد. پس از فلوتاسیون پیریت، 38 درصد از طلای موجود در کانسنگ، با عیار حدود ppm8 با بازیابی وزنی 8/3 درصد بازیابی شد که با سیانوراسیون کنسانتره فلوتاسیون پیریت، طلا قابل دستیابی است که این خود می تواند یک پیش تغلیظ مناسب باشد. شرایط بهینه فلوتاسیون پیریت برای حداکثر بازیابی طلا عبارتند از: 9pH=، درصد جامد 25، کلکتور آمیل گزنتات پتاسیم با مقدار بهینه 150 گرم بر تن، دانه بندی d80 برابر با 150 میکرون، مقدار ppm25 کف ساز MIBC و مدت زمان آماده سازی 10 دقیقه بود. با استفاده از آنالیز گوگرد، مشخص شد که حدود 2/92 درصد از پیریت موجود در نمونه با فلوتاسیون بازیابی شده است. همچنین تصاویر EPMA نشان دادند که طلای موجود در کانسنگ طلای موته، به صورت درگیر با پیریت وجود دارد که با خردایش بیشتر، طلا قابل آزاد شدن است. اندازه ذرات طلای آزاد شده در تصاویر EPMA، 4-3 میکرون، تشخیص داده شد. با توجه به نتایج لیچینگ تشخیصی بر روی نمونه موجود و همچنین آزمایش های فلوتاسیون کوارتز، هیچ گونه طلای درگیر، درون کانی های سیلیکاته گزارش نشد و با فلوتاسیون کوارتز و حذف 34/24 درصد وزنی از بار ورودی، می توان بار ورودی به مرحله لیچینگ سیانیدی را کاهش داد که این نیز می تواند یک پیش تغلیظ مناسب باشد که باید مورد بررسی بیشتر واقع شود.کلید واژگان: موته، پیریت، طلا، کوارتز، فلوتاسیونThe aim of the present study is to decrease the amount of unwanted gangue minerals to enter the cyanidation process. The flotation process was introduced for the beneficiation of the feed to the cyanide leaching stage. Selection of a proper procedure for gold processing needs the accurate characterization of the gold bearing minerals comprising the ore. Diagnostic leaching tests were conducted to specify the gold mineral phases and associated gold in Mouteh ore. Fire assay analysis showed gold grade equal to 0.85 ppm and 0.86 ppm for the two representative samples of Mouteh plant feed. In pyrite flotation tests, the recovery and grade of gold in concentrate were found to be 38% and 8ppm, respectively. The cyanidation of concentrate can lead to an efficient beneficiation process for the gold recovery. The optimized conditions was found to be: pH: 9, solid percent: 25, potassium xanthate (KAX) as collector: 150 gr/t, MIBC as frother: 25ppm , and conditioning time: 10 minute. EPMA analysis demonstrated that gold in Mouteh ore was associated with pyrite which would need more grinding for liberation. The size of liberated gold particles in EPMA pictures was found to be 3-4 microns. According to the diagnostic leaching experiments and silicates flotation tests, no gold was detected with silicates mineral. Following the flotation of quartz particles and elimination of 20 percent of feed by weight, it would be possible to reduce the feed of cyanide leaching. Therefore, Quartz flotation can also be an effective pre-concentration method prior to cyanidation process.Keywords: Mouteh, Diagnostic leaching, Gold, Quartz
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محدوده اکتشافی خونی در270 کیلومتری استاناصفهان در منطقه انارک و در زون ایران مرکزی واقع شده است. با توجه به وجود شواهدی حاکی از کانی سازی طلا در این ناحیه، شناسایی نواحی امید بخش معدنی در این منطقه ضروری است. بنابراین ضرورت یافتن اطلاعاتی در مورد ارتباط و چگونگی رفتار عناصر طلا، آرسنیک و آنتیموان نسبت به یکدیگر در این محدوده، برای پیدایش و تعیین وسعت هاله های ژئوشیمیایی، تعیین امیدبخش بودن منطقه و تخمین عیار اهمیت می یابد و باید مورد بررسی قرار گیرند. بدین منظوردر تحقیق حاضر برای تعیین رفتار عناصر نام برده، با استفاده از روش معروف و کارآمد K-means انجام می شود که یکی از روش های خوشه بندی بوده و مبتنی بر کمینه نمودن مجموع فواصل اقلیدسی هر یک از نمونه ها از مرکز دسته ای که به آن تخصیص می یابد، است. در این پژوهش از تابع کیفیت خوشه بندی و میزان مطلوبیت نمونه در خوشه مورد نظر (S(i))، برای تعیین تعداد خوشه بهینه استفاده شده است و در پایان با توجه به مراکز خوشه ها و نتایج حاصل، معادله ای جهت تخمین عیار عنصر طلا بر حسب چهار پارامتر عیار آرسنیک، عیار آنتیموان، طول و عرض نقاط نمونه برداری ارائه می شود.کلید واژگان: طلا، کانسار خونی، روش خوشه بندی، تخمین عیار، K، MeansJournal of Aalytical and Numerical Methods in Mining Engineering, Volume:5 Issue: 10, 2016, PP 77 -92Khooni exploratory area is located at 270 kilometers of Esfahan, and belongs to Central Iran geological zone. According to some instances expressing gold mineral forming in this area, make reconnaissance of favorable area as an essential fact. A well-known algorithm of clustering is K-Means by which the data are divided into K clusters on the basis of distance. In this analysis, using the K-Means method to classify the sampling of khooni district for Gold, Arsenic and Antimony elements. The optimal K value was determined and then the data were clustered and the behavioral characteristics were analyzed, and at the end relationships and equations with correlation coefficients were identified and the grade of gold were estimated based on four parameters Arsenic, Antimony content; length and width of the sampling points.Keywords: Gold, khooni deposits, clustering, estimated grade, K, Means
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This study investigates the optimization of gold dissolution from Aghdarre ore. Therefore, a laboratory investigation was initiated, to improve the leaching conditions with the objective of maximizing mill capacity with no reduction on gold recovery. It was observed that the time reduction from 25 to 15 hours did not change the gold recovery. In the other words, it indicated that a capacity of 140t/h can be sustained without detrimental effect on gold recovery. The optimum parameters were 700g/t NaCN, 46% solid in pulp, pH=10, and d80=45 microns using the Taguchi method. So, the gold recovery was obtained 90.71%. Also, it was concluded that the NaCN concentration was the most effective parameter and the solid percent plus retention time had the lowest effects on this process.Keywords: Optimization, Cyanidation, Gold, Tagouchi, Aghdarre
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Since a high toxicity of cyanide which use as a reagent in the gold processing plant, thiosulfate has been recognized as a environmental friendly reagent for leaching of gold from ore. After gold leaching process it''s important for recovery of gold from solution using adsorption or extraction methods, One of these methods is activated carbon.The loading of gold from industrial thiosulfate solution that obtained from Zarshuran gold plant-Takab-Iran, onto activated carbon have been investigated. The affecting variables of the adsorption of gold on the carbon included, temperature, concentration of gold, size of activated carbon, pH and the ratio of amount of activated carbon to the volume of solution. The results have shown that at low concentration of gold, effective loading can be achieved at pH 10.5. The size of activated carbon has a significant effect on the loading of gold. In this research the recovery of gold on activated carbon has been predicted using artificial neural network. For this purpose temperature, pH, the proportion of solution volume to weight of activated carbon, gold concentration and time of adsorption were taken as input parameters, whereas, the recovery of gold on activated carbon from thiosulfate solution was considered as an output parameter. The network with LMBP algorithm with two hidden layer were used and the topology 5-4-13-1 showed the best ability for prediction.Moreover sensitive analyze were indicated parameters pH and temperature have substantial influence on adsorption.Keywords: Thiosulfate, gold, activated carbon, zarshuran gold plant, artificial neural network
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