به جمع مشترکان مگیران بپیوندید!

تنها با پرداخت 70 هزارتومان حق اشتراک سالانه به متن مقالات دسترسی داشته باشید و 100 مقاله را بدون هزینه دیگری دریافت کنید.

برای پرداخت حق اشتراک اگر عضو هستید وارد شوید در غیر این صورت حساب کاربری جدید ایجاد کنید

عضویت

جستجوی مقالات مرتبط با کلیدواژه « Wastewater » در نشریات گروه « پزشکی »

  • Zeinab Parmoozeh, Gholamreza Reza Mostafaii, Davarkhah Rabbani, Hossein Akbari, Atieh Salem, Mohammadbagher Miranzadeh*
    Background

    The growing use of treated wastewater in farming has raised concerns about the potential impacts on public health.

    Methods

    This study assessed the levels of the heavy metals lead (Pb), cadmium (Cd), and arsenic (As) in plants watered in greenhouse settings using both well water and synthetic wastewater. Synthetic wastewater with As at concentrations of 0.1, 0.2, and 0.4 mg/L, Pb at 1, 3, and 5 mg/L, and Cd at 0.01, 0.03, and 0.05 mg/L, as well as well water were used to irrigate radish, coriander, and grass. In the end, 144 vegetable samples were gathered, and inductively coupled plasma-optical emission spectrometry (ICP-OES) was used to determine the heavy metal concentrations in the samples. Risk assessment for consumers was determined based on the measured levels of heavy metals in the vegetables.

    Results

    Even though the concentrations of heavy metals in the wastewater were within the limits for irrigation, the risk assessment showed that consumption of vegetables irrigated with treatment wastewater could pose risks to individuals’ health. The maximum concentration of Pb in radish leaves was observed at the Pb concentration of 5 mg/L, and the maximum concentration of As in cress irrigated with As effluent at the As concentration of 0.02 mg/L.

    Conclusion

    The consumption of vegetables containing Pb can pose a significant non-carcinogenic risk to consumers. However, well water may also be dangerous in the long run. Therefore, it is important to ensure about food safety when using treated wastewater for irrigation.

    Keywords: Arsenic, Lead, Vegetables, Wastewater, Risk Assessment}
  • Kamyar Yaghmaeian, Masoud Panahi Fard, Mehdi Ahmadi Moghadam, Maryam Mousavi, Neematollah Jaafarzadeh*, Maryam Omidinasab, Bamshad Shenavar, Rozhan Feizi
    Background

    Wastewater treatment plants are important sources of emissions of greenhouse gases (GHSs) such as carbon dioxide and methane in the atmosphere. Also, energy consumption in the wastewater treatment process causes indirect carbon dioxide emissions.

    Methods

    One hundred thirty-three operating wastewater treatment plants in Iran treat municipal wastewater. The carbon dioxide and methane emissions from the wastewater treatment plants for the year 2022 were estimated by establishing a calculation model according to the methods recommended by the Intergovernmental Panel on Climate Change for National Greenhouse Gas Inventories (2006) and United States Environmental Protection Agency (USEPA) guidelines.

    Results

    Based on the Intergovernmental Panel on Climate Change guideline, the total methane emission was 158.63 tons. Based on the USEPA guideline, the total emissions of methane and carbon dioxide were 47.61 and 351.47 tons, respectively. This amount is 3.2% of all the methane and carbon dioxide emissions of Iran. Isfahan and Tehran provinces have the highest emissions rates of methane at 31.85 and 22.91 tons, respectively. While South Khorasan and Kerman provinces have the lowest methane emissions rates of 0.46 and 0.67 tons, respectively.

    Conclusion

    The results will provide a scientific basis and effective strategies for policymakers to reduce the methane and carbon dioxide emissions from the wastewater treatment plants of Iran.

    Keywords: Methane, Carbon Dioxide, Greenhouse Gases, Wastewater, Iran}
  • نسرین هاشمی، مسعود هنرور*، الهه قره خانی

    آلودگی آب با فلزات سنگین سمی در اثر تخلیه فاضلاب صنعتی یک مشکل زیست محیطی در سراسر جهان است. حذف فلزات سنگین از پساب صنعتی موضوعی قابل توجه در زمینه آلودگی آب است که یک معضل جدی در کاهش کیفیت آب می باشد. فلزات متعددی مانند نیکل، کادمیوم، کروم، کبالت، مس، سرب، جیوه و روی به میزان قابل توجهی سمی می باشند. هدف از این مطالعه بررسی تاثیر پوست انار به عنوان یک جاذب ارزان قیمت در حذف فلزات نیکل و کروم می باشد. پوست های انار ابتدا با محلول سود 1/0 نرمال اصلاح شد و توانایی جذب بررسی گردید. تاثیر سود بر روی جاذب توسط تکنیک های CHN، FT-IR، و SEM مورد بررسی و ارزیابی قرار گرفت. نتایج نشان داد که اصلاح جاذب با سود در حذف یون های کروم و نیکل از پساب صنعتی موثر بوده است. آزمایشات جذب در غلظت های مختلف جاذب، زمان، دما و pH های مختلف انجام گرفت. تجزیه و تحلیل داده‎ها نشان می‎دهد که شرایط بهینه برای یون نیکل (II) g/L 4.5 از جاذب، 6pH=، دما308.15 K و زمان 60 دقیقه و شرایط بهینه برای یون کروم (VI)، g/L 4 از جاذب، 5.5pH= ، دمای 300.65K و زمان 100 دقیقه می باشد. تحقیقات صورت گرفته و نتایج حاصل از آن با توجه به مزایای بالقوه، استفاده از این جاذب به عنوان جاذب زیستی جهت حذف نیکل و کروم در پساب صنعتی را به عنوان چشم اندازی امیدوار کننده و دوستدار محیط زیست پیشنهاد می کند.

    کلید واژگان: آلودگی, فلزات سنگین, پوست انار, فاضلاب, جذب}
    Nasrin Hashemi, Masoud Honarvar *, Elahe Gharekhani

    Water pollution with toxic heavy metals due to industrial wastewater discharge is a global environmental issue. The removal of heavy metals from industrial effluents is a significant concern in the field of water pollution and a serious challenge in reducing water quality. Multiple metals such as nickel, cadmium, chromium, cobalt, copper, lead, mercury, and zinc are notably toxic. The aim of this study is to investigate the impact of pomegranate peel as a cost-effective adsorbent in removing nickel and chromium metals. Pomegranate peels were initially treated with a 0.1 N sulfuric acid solution, and their adsorption capacity was examined. The effect of sulfuric acid on the adsorbent was assessed using CHN, FT-IR, and SEM techniques. The results indicated that the modification of the adsorbent with sulfuric acid was effective in removing chromium and nickel ions from industrial wastewater. Adsorption experiments were carried out at various adsorbent concentrations, times, temperatures, and pH levels. Data analysis revealed that the optimal conditions for nickel ions (II) are a concentration of 4.5 g/L of the adsorbent, pH 6, a temperature of 308.15 K, and a time of 60 minutes. The optimal conditions for chromium ions (VI) are a concentration of 4 g/L of the adsorbent, pH 5.5, a temperature of 300.65 K, and a time of 100 minutes. The research conducted and the results obtained suggest that, considering the potential benefits, the use of this adsorbent for the removal of nickel and chromium in industrial wastewater is a promising and environmentally friendly approach.

    Keywords: Keywords, Pollution, Heavy Metals, Pomegranate Peel, Wastewater, Adsorption}
  • Abdoreza Ahaki Varzaneh, Rouhullah Dehghani*, Marzieh Akbari, Zahra Bagheri Varzaneh, Somaye Dolatabadi Arani, Saeid Fadaei, Reza Ali Fallahzadeh
    Introduction

    Phytoremediation is a sustainable, cost-effective, and environmentally friendly process that utilizes plants and microorganisms for purification of the polluted land. In this study, the fast-growing species Salix acmophylla from the Salicaceae family was selected for phytoremediation purposes.

    Materials and Methods

    With the aim of exploring the potential of Salix acmophylla in wastewater purification, a research initiative was launched in 2020, Following initial land preparation on a 5-hectare site next to a wastewater treatment plant, 60,000 Salix acmophylla cuttings were planted. By 2022, the trees had matured to a height of 3-4 meters. Wastewater samples were then collected and analyzed for pollutant levels both before entering the planted area and after passing through drainage channels built among the trees. This allowed researchers to calculate the average efficiency of Salix acmophylla in reducing wastewater pollutants.  

    Results

    The results regarding the impact of Salix acmophylla trees on the reduction of wastewater Characteristics in the cultivation area were the following: COD, BOD5, TSS, TDS, EC, and turbidity exhibited reductions of 38%, 42%, 17.5%, 79%, 52.2%, and 45.6%, respectively. Additionally, the estimated income from the cultivation of these trees was approximately $49,000.

    Conclusion

    Planting Salix acmophylla trees significantly contributes to the reduction of wastewater pollutant parameters, suggesting the recommendation of this species for similar climates.

    Keywords: Phytoremediation, Removal, Isfahan City, Wastewater}
  • Mahsa Rahrovan, Hasan Rahmani *, Davarkhak Rabbani, MohammadBagher Miranzadeh, Habiballah Rahimi
    Background

    Vancomycin (VCM) is a critical antibiotic due to its high consumption and side effects, including increased bacterialresistance affecting treatment processes. This research investigated the efficiency of VCM antibiotic removal from an aqueoussolution using a UV/Fe3O4@Alg-ZnO integrated process.

    Methods

    Response surface methodology (RSM) and a Box-Behnken design were applied using Design-Expert software tooptimize the number of samples and simultaneously understand the interactive effects between variables. X-ray diffraction (XRD),a vibrating-sample magnetometer (VSM), field effect scanning electron microscopy (FE-SEM), and Fourier transform infrared(FTIR) analyses were used to check the structural characteristics. The effects of initial catalyst concentration (0.1, 0.3, and 0.5g/L), initial pollutant concentration (10, 30, and 50 mg/L), contact time (10, 30, and 50 minutes), and pH (3, 7, and 11) on VCMdecomposition rate were investigated. Spectrophotometry, total organic carbon (TOC), and GC-MS analyses were used to checkthe efficiency of the process.

    Results

    In this study, VCM and TOC removal efficiency was 92.64% and 85.38%, respectively, under optimal conditions. Thereason for the reduction in the efficiency of the combined UV/Fe3O4@Alg-ZnO process in real raw sewage, after activated sludge(13%) and after activated sludge and stabilization ponds (24%), is the high COD, which causes the active radicals produced tobe spent on other species instead of the VCM antibiotic.

    Conclusion

    The current study showed that the UV/Fe3O4@Alg-ZnO process performs well in removing VCM and TOC. In realwastewater, this efficiency was significantly reduced.

    Keywords: Photocatalysis, Vancomycin antibiotic removal, Wastewater, UV, Fe3O4@Alg-ZnO, Response surface methodolog}
  • انور اسدی، یحیی سلیمی، نگین فرهادیان*
    زمینه و هدف

    پایش مصرف الکل در جامعه برای برنامه ریزی بهداشت عمومی و ارزیابی کارایی راهبردهای مداخلاتی اهمیت بالایی دارد. هدف از این مطالعه، استفاده از روش اپیدمیولوژی بر پایه فاضلاب برای تخمین مصرف الکل در جمعیت تحت پوشش تصفیه خانه فاضلاب شهر کرمانشاه و همچنین ارزیابی میزان ریسک بهداشتی آن با روش حاشیه مواجهه (Margin of Exposure, MOE) می باشد.

    مواد و روش ها

    نمونه های مرکب روزانه (5 ساعتی) از ورودی تصفیه خانه فاضلاب کرمانشاه در سال 1400 برای یک دوره زمانی 30 روزه جمع آوری شدند. برای سنجش میزان الکل نمونه ها از متابولیت اتیل سولفات استفاده شد که بعد از مصرف الکل توسط انسان در ادرار دفع می شود و وارد شبکه جمع آوری فاضلاب می گردد. نمونه ها بعد از سانتریفیوژ و فیلتراسیون مستقیما به دستگاه liquid chromatography with tandem mass spectrometry LC-MS/MS برای آنالیز تزریق گردید. بعد از محاسبه سرانه مصرف الکل با روش محاسبه معکوس از نتایج آن برای ارزیابی ریسک بهداشتی با روش MOE استفاده شد.

    یافته ها

     میانگین سرانه میزان مصرف الکل در طول دوره نمونه برداری جامعه تحت مطالعه برابر0/332 میلی لیتر به ازای هر نفر با سن برابر و بالای 15 سال (فرد بالغ) در روز بود که در طول یکسال برابر 0/121 لیتر الکل خالص به ازای هر نفر خواهد شد. بین میزان مصرف الکل در روزهای آخر هفته با روزهای کاری هفته و همچنین روزهای نمونه گیری واقع در رمضان و روزهای عادی تفاوت معنی داری مشاهده نشد. در 90 درصد نمونه های برداشت شده، ریسک ناشی از مصرف الکل بالاتر از 100= MOE بوده (محدوده حفاظتی) و تنها در 3 نمونه مقدار MOE در محدوده "خطر" قرار گرفت.

    نتیجه گیری

    روش اپیدمیولوژی بر پایه فاضلاب می تواند اطلاعات زمانی و موقتی مناسبی در ارتباط با مصرف الکل و خطر مرتبط با آن از لحاظ مواجهه در سطح جامعه فراهم کند. میزان مصرف الکل در جامعه مورد مطالعه نسبت به کشورهای اروپایی و آمریکایی بسیار کمتر بود.

    کلید واژگان: فاضلاب, اپیدمیولوژی بر پایه فاضلاب, الکل, اتیل سولفات, حاشیه مواجهه, کرمانشاه}
    Anvar Asadi, Yahya Salimi, Negin Farhadian*
    Background and Aim

    Monitoring alcohol consumption in population is very important for planning public health and evaluation of the efficiency of intervention strategies. The aim of this study was to use wastewater-based epidemiology (WBE) to estimate alcohol consumption in a Kermanshah City and calculate risk assessment using the margin of exposure (MOE) approach.

    Materials and Methods

    Raw composite wastewater samples (5 hours) were collected form the entrance of Kermanshah wastewater plant over a 30 days’ period. Ethyl sulfate metabolite was used to measure the alcohol content of the samples, which is excreted in the urine after consuming alcohol by humans and enters into the wastewater collection network. After centrifugation and filtration, the samples were directly injected into the liquid chromatography with tandem mass spectrometry LC-MS/MS for analysis. After calculation of alcohol consumption rate with back-calculation method, the results were used for risk assessment by MOE.

    Results

    In general, the average amount of alcohol consumption during sampling in the society was 0.332 ml per person of equal age and over 15 years of age (adult) per day, which was equal to 0.121 liters of pure alcohol per person per year. We found no significant difference in the amount of alcohol consumption between the weekend and working days of the week, and also between  sampling days in Ramadan and ordinary  days. In 90% of the samples taken, the risk associated with alcohol consumption was higher than MOE=100 and only in 3 samples the MOE value was in the "risk" category.

    Conclusion

    The results of this study showed that wastewater-based epidemiology can provide appropriate timely and transisional  information on alcohol use and its associated exposure risks in the community. Also, the amount of alcohol consumption in the population in our study was much lower than those in the European and American countries.

    Keywords: Wastewater, Wastewater epidemiology, Alcohol, Ethyl sulfate, Margin of exposure, Kermanshah}
  • Sri Slamet Mulyati, Nia Yuniarti Hasan, Ade Kamaludin, Redi Yudha Irianto, Salma Aripin*
    Background

    Inappropriate management of textile wastewater results in environmental pollution. To counter this, biofilters or biofilm systems serve as alternatives. Biofilters work like a filter, with a media stack that aids in the filtration process. In this study, pozzolan and sawdust were used as media. The present study aimed to identify the difference in average color content, chemical oxygen demand (COD), and chromium of textile wastewater after passing through a single biofilter versus a combination biofilter.

    Methods

    This study employs a post-test with a control design experimental research design. The research population is the total textile wastewater produced by the X industry located in Cimahi city, Indonesia. The grab sampling technique was employed to collect 30 L of textile wastewater for each treatment using both the single biofilter (composed solely of sawdust) and the combination biofilter (mixture of sawdust and pozzolan).

    Results

    There are significant differences in color, COD, and chromium content averages between single and combined biofilter treatments, supported by P values of 0.012, 0.004, and 0.010. The single biofilter exhibited higher percentage reductions in color and chromium (14.25% and 90.83%, respectively) compared to the combination biofilter. In contrast, the combination biofilter achieved a remarkable COD reduction of up to 79.45%compared to the single biofilter.

    Conclusion

    The results of the present study showed that the single biofilter had a higher capacity to remove color and chromium compared to the combination biofilter. Meanwhile, the combination biofilter was found to be more effective in removing COD compared to the single biofilter.

    Keywords: Wastewater, Chromium, Water purification, Textiles, Biofilms}
  • Parisa Javanbakht, Mehdi Vosoughi, Zahra Noorimotlagh, Abdollah Dargahi, Chiman Karami*
    Background

    The occurrence of COVID-19 as a public health emergency of international alarm was declared by the World Health Organization (WHO) on January 30, 2020. The identified transmission path is due to direct close contact or via respirational droplets. There is uncertainty about other ways, such as transmission of surfaces, air, and other sources. This study follows the preferred reporting items for systematic reviews and meta-analysis guidelines to investigate severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) virus in environmental surfaces, water, wastewater, and air.

    Materials and Methods

    In this study, we performed a systematic literature search in PubMed (MEDLINE), Scopus, and Web of Science (ISI) databases in August 2022. The investigation on electronic databases resulted in a total of 2049 articles. A total of 249 potentially relevant were identified for full-text evaluation. Meanwhile, 30 articles were included in the synthesis.

    Results

    According to four included studies, negative detection of SARS-CoV-2 transmission in water is established. A laboratory study has shown that viable SARS-CoV-2 could be found in aerosols for about 3 h. Also, the virus can be found on dry surfaces, depending on the material of the surface, for 8 to 72 h. Our results showed it is possible to exciting SARS-CoVs in air, environmental surface, and wastewater. 

    Conclusion

    These results can help healthy policymakers make suitable assessments of main prevention measures.

    Keywords: SARS CoV-2, Air, Water, Surface, Wastewater}
  • Zohreh Rahaei, MohammadTaghi Ghaneian, Fatemeh Hasanzadeh Mohammadi*, MohammadHassan Ehrampoush, Sara Jambarsang, Seyyed Vahid Ghelmani
    Introduction

    Droughts and precipitation imbalances in various parts of the world have underscored the significance of alternative water resources. In recent years, recycled water has emerged as a viable alternative, with wastewater being treated to a safe level for diverse purposes. However, the public acceptance of water reuse plays a pivotal role in determining the success of recycling initiatives. This study aims to identify the barriers and facilitators influencing public acceptance of water reuse in Yazd, Iran, during 2020.

    Material and Methods

    A cross-sectional study involving 384 individuals in Yazd city during 2020 was conducted. Participants were selected using the stratified sampling method. The data collection tool was a researcher-made questionnaire. Data were analyzed using descriptive statistics and the Pearson correlation test in SPSS software version 23.

    Results

    The most crucial facilitator for acceptance was the concept of segregating drinking water and recycled water networks. The primary barrier to acceptance was the perceived risk of recycled water contamination and potential health hazards. Water reuse was most widely accepted for construction purposes, followed by toilet flush tanks and irrigation of green spaces in parks and sports fields. A positive correlation (r = 0.416) existed between facilitators and acceptance of water reuse, indicating that enhancing facilitators positively affected acceptance.

    Conclusion

    To successfully implement water reuse projects, it is essential to consider key facilitators such as segregated water systems for different household uses, raising public awareness about the benefits of water reuse, and building public trust in recycled water safety.

    Keywords: Attitude, Public Health, Wastewater, Yazd City}
  • Pardis Mokri, Bahareh Rahimian Zarif, Sirwan Mohammadi Azar, Bahram Ebrahimi *
    Background
    Bio-remediation methods of organic pollutants are promising due to their high efficiency, low cost, and green chemistry. These methods are effective alternatives to traditional elimination methods.
    Methods
    Bacillus cereus PTCC 1015S strain was used to eliminate acid blue 113 (AB113) and acid orange 7 (AO7) from aqueous solutions. The bacteria were activated in the Luria Bertani Broth (MILLER) culture medium. The effective parameters such as incubation time and temperature, pH of dye solution, dye concentration, and the bacterial inoculation quantity on decolorization were investigated. Kinetic and thermodynamic studies were done to clarify the different aspects of the introduced method. Also, the reliability of the method to remove studied dyes was investigated in dye factory wastewater samples.
    Results
    The first-order kinetic model was the best model to describe the kinetics of decolorization. The obtained thermodynamic data showed that the elimination process was endothermic (ΔH0 = + 29.03, 30.53) while it was spontaneous (ΔG0 < 0) for both studied dyes and so entropy change (ΔS0 = + 109.63, 116.32) was an effective force in the decolorization. Under optimized conditions, B. cereus PTCC 1015S showed high average removal; 98.5 and 99.3 % for AB113 and AO7 respectively in dye model solutions. The removal efficiency was more than 85 % for bothstudied dyes in wastewater spiked samples.
    Conclusions
    The B. cereus PTCC 1015 strain was capable of being exploited in the removal of AB113 and AO7 dye molecules as an affordable and eco-amiable method for the treatment of aqueous samples contaminated with the studied azo dyes.
    Keywords: Dye elimination, Bio-remediation, Bacterial medium, Wastewater}
  • Lelisa Regea Mengistu, Chali Dereje Kitila*
    Background

    Electrocoagulation is becoming a promising eco-friendly wastewater treatment technique. It is a low-cost wastewater treatment method suitably applied for various wastewater effluent characteristics. Nevertheless, there are different kinds of electrocoagulation; comparison among them in terms of nutrient removal is investigated in the present research. This study analyzed nitrate (NO3-) and phosphate (PO43-) removal potential of the sono-alternative and direct-current electrocoagulation process.

    Methods

    Batch reactor and sono-direct current (SDC)/sono-alternative current (SAC) electrocoagulation cell were employed to investigate NO3- and PO43- removal efficiency from domestic effluents. The data gathered from laboratory experiments were analyzed using response surface methodology (RSM). ANOVA was used to examine the interaction effects of diverse parameters in terms of NO3_ and PO43- removal from domestic wastewater effluents.

    Results

    At extreme experimental conditions, the percentage of NO3- and PO43- removal attained with sono-direct current electrocoagulation (SDCE) and sono-alternative current electrocoagulation (SACE) were 96.5%, 96.2% and 96.8%, 96.5, respectively. The SACE was more successful in eliminating NO3-and PO43- than the SDCE process. The appearance of resistant oxide coating on the cathode and the appearance of corrosion on the anode due to oxidation processes in the case of SDCE were identified as principal factors highly affecting NO3- and PO43- removal efficiency.

    Conclusion

    With optimum process efficiency, experimental findings show that the SACE process is more capable of NO3- and PO43- removal than the SDCE process.

    Keywords: Electrocoagulation, Nitrates, Phosphates, Wastewater, Water purification}
  • فریده روستائی، مجید بغدادی*، اعظم مرجانی، محمد علیمرادی
    مقدمه

    بیس فنل آ یکی از ریزآلاینده های نوظهور شناخته شده می باشد که اثرات مخربی بر سلامت انسان دارد. این آلاینده از طریق تخلیه پساب تصفیه خانه های فاضلاب شهری به محیط زیست راه پیدا می کند. در پژوهش حاضر، روش ریزاستخراج مایع- مایع پخشی بر پایه اثر بیرون رانی نمک (Salting out assisted liquid-liquid microextraction یا SA-LLME) جهت پیش تغلیظ بیس فنل آ در نمونه های آب شرب و پساب فاضلاب شهری مورد بررسی قرار گرفت. این روش به دلیل فاکتور تغلیظ بالا، اندازه گیری مقادیر ناچیز بیس فنل آ را در نمونه های مورد بررسی امکان پذیر می کند.

    روش ها

    در این روش، بیس فنل آ با 4-آمینوآنتی پیرین در حضور پتاسیم هگزاسیانوفرات یک مشتق آب گریز رنگی آنتی پیرین تشکیل می دهد. جهت استخراج مشتق حاصل شده، 250 میکرولیتر از 2-فنوکسی اتانول در 10 میلی لیتر نمونه حل گردید. سپس با اضافه کردن 7/0 گرم کلرید سدیم به نمونه، قطرات ریزحلال استخراج کننده در نمونه تشکیل و محلول ابری شد. بعد از سانتریفوژ، فاز استخراج کننده حاوی مشتق بیس فنل آ در ته لوله آزمایش ته نشین و سپس به منظور کاهش ویسکوزیته، به آن 20 میکرولیتر متانول اضافه گردید. اندازه گیری به وسیله دستگاه کروماتوگرافی مایع با راندمان بالا (High-performance liquid chromatography یا HPLC) در طول موج 480 نانومترانجام شد. برای بهینه سازی فرایند، اثر مقدار 4-آمینوآنتی پیرین، پتاسیم هگزاسیانوفرات، سدیم کلرید و بافر مورد بررسی قرار گرفت. سپس ارقام شایستگی روش به دست آمد و عملکرد روش روی نمونه های آب شرب و پساب فاضلاب شهری ارزیابی گردید.

    یافته ها

    تحت شرایط بهینه (2-فنوکسی اتانول: 250 میکرولیتر، 4-آمینوآنتی پیرین 1 درصد: 100 میکرولیتر، پتاسیم هگزاسیانوفرات 10 درصد: 80 میکرولیتر و بافر 10 = pH: 10 میکرولیتر و سدیم کلرید: 7/0 گرم بر 10 میلی لیتر نمونه)، فاکتور تغلیظ 106 و حد تشخیص (Limit of detection یا LOD) 1/0 نانوگرم بر میلی لیتر، حد کمی سازی 3/0 نانوگرم بر میلی لیتر و انحراف استاندارد نسبی (Relative standard deviation یا RSD) 2/3 درصد به دست آمد. ضریب همبستگی (Correlation coefficient یا CC) منحنی کالیبراسیون، 9985/0 بود. نتایج آنالیز نمونه های آب و پساب نیز نشان داد که روش توسعه یافته عملکرد مناسبی جهت اندازه گیری بیس فنل آ در نمونه های با ماتریکس واقعی دارد.

    نتیجه گیری

    با توجه به حدتشخیص پایین، فاکتور تغلیظ بالا و عملکرد مناسب در نمونه های واقعی، این روش را می توان به عنوان یک روش حساس و کارامد جهت اندازه گیری مقادیر بسیار پایین بیس فنل آ در نمونه های آب و پساب معرفی نمود.

    کلید واژگان: آب, پساب, ریزاستخراج فاز مایع, بیس فنل آ, اندازه گیری, کروماتوگرافی مایع}
    Farideh Roustaei, Majid Baghdadi*, Azam Marjani, Mohammad Alimoradi
    Background

    Bisphenol A is known as one of the emerging micropollutants with harmful effects on human health. This pollutant enters the environment through the discharge of municipal wastewater treatment plants. In this research, the salting out dispersive liquid-liquid microextraction method was investigated for pre-concentration of bisphenol A in drinking water and urban sewage effluent samples. Due to the high enrichment factor, this method enables the measurement of small amounts of bisphenol A in the examined samples.

    Methods

    In this method, bisphenol A forms a colored hydrophobic derivative of antipyrine with 4-aminoantipyrine in the presence of potassium hexacyanoferrate. In order to extract the resulting derivative, 250 µl of 2-phenoxyethanol was dissolved in 10 ml of the sample. Then, by adding 0.7 g of sodium chloride to the sample, fine droplets of extracting solvent were formed in the sample and the solution became cloudy. After centrifugation, the extraction phase containing bisphenol A derivative settled at the bottom of the test tube, and then, 20 µl of methanol was added in order to reduce its viscosity. The measurement was performed by a high-performance liquid chromatography at a wavelength of 480 nm. To optimize the process, the effect of the amount of 4-aminoantipyrine, potassium hexacyanoferrate, and buffer was investigated. Then, the figures of merit of the method were obtained and the performance of the method was evaluated on drinking water and urban sewage effluent samples.

    Findings

    Under optimal conditions (2-phenoxyethanol: 250 µl, 4-aminoantipyrine 1%: 100 µl, potassium hexacyanoferrate 10%: 80 µl, buffer pH 10: 10 µl, and sodium chloride: 0.7 g per 10 ml of sample), the enrichment factor of 106, the detection limit of 0.1 ng ml-1, the limit of quantification of 0.3 ng ml-1, and the relative standard deviation (RSD) of 3.2% were obtained. Meanwhile, the correlation coefficient (CC) of the calibration curve was equal to 0.9985. Moreover, the results of the analysis of water and urban sewage effluent samples showed that the developed method had suitable performance for the measurement of bisphenol A in real matrix samples.

    Conclusion

    Considering the low detection limit, high enrichment factor, and proper performance in real samples, this method can be introduced as a sensitive and efficient method for the measurement of very low amounts of bisphenol A in water and wastewater samples.

    Keywords: Water, Wastewater, Liquid phase microextraction, Bisphenol A, Measurement, Liquid chromatography}
  • فرشید سلیمانی، رضا طاهرخانی، سینا دوبرادران*، فاطمه فرشادپور، عاطفه خلیلی درودزنی، مرضیه طاهرزاده
    زمینه

    تک یاخته کریپتوسپوریدیوم از انگل های بیماری زای روده ای در آب و هوای گرم و مکان هایی که تصفیه آب و فاضلاب کمتر موثر است، شیوع بیشتری دارند. هدف از این مطالعه تشخیص و شناسایی کریپتوسپوریدیوم در فاضلاب شهری خام ورودی به منطقه ساحلی در شهر بوشهر بود.

    مواد و روش ها

    در مجموع در دو فصل زمستان و تابستان 48 نمونه فاضلاب خام شهری از 8 ایستگاه برداشت شد. نمونه های فاضلاب از طریق الک 300 میکرومتری برای حذف ذرات بزرگ و سپس بر روی غشای استات سلولز، با اندازه منافذ 2/1 میکرومتر فیلتر شدند. فیلترها خراشیده و با استفاده از 40 میلی لیتر سالین بافر فسفات (PBS) حاوی 05/0 درصد TWEEN شسته شدند و سپس با دور 5000 به مدت 10 دقیقه در دمای 4 درجه سانتی گراد سانتریفیوژ شد. از چرخه ی انجماد و ذوب برای استخراج DNA استفاده شد. سطح DNA استخراج شده با نانو دراپ (اسپکتروفتومتر، ND1000) اندازه گیری شد و محصولات PCR با الکتروفورز در ژل آگارز 2 درصد جدا شدند.

    یافته ها

    نتایج آنالیز PCR نشان داد که از 48 نمونه، 17 نمونه (4/35 درصد) در مورد کریپتوسپوریدیوم با استفاده از nested-PCR مثبت شدند. در مجموع به ترتیب 11 و 6 نمونه در فصل زمستان و تابستان مثبت بودند.

    نتیجه گیری

    مقامات محلی بایستی با توجه و بکارگیری فرآیندهای تصفیه فاضلاب از اپیدمی های احتمالی کریپتوسپوریدیوز بین ساکنین و همچنین به کاهش انتقال کریپتوسپوریدیوز انسانی و حیوانی کمک کنند.

    کلید واژگان: کریپتوسپوریدیوم, فاضلاب, PCR, بوشهر, خلیج فارس}
    Farshid Soleimani, Reza Taherkhani, Sina Dobaradaran*, Fatemeh Farshadpour, Atefeh Khalili Doroodzani, Marzeah Taherzadeh
    Background

    The protozoan Cryptosporidium is an intestinal pathogenic parasite; are more common in hot climates and places where water and sewage treatment is less effective. The aim of this study was to detect Cryptosporidium in raw urban wastewaters entering the Bushehr coastal area. 

    Materials and Methods

    In total, 48 samples of urban raw wastewater samples were collected from 8 stations in winter and summer seasones. Wastewater samples were filtered through a 300 μm sieve to re-move large particles and then on a cellulose acetate membrane with a pore size of 1.2 μm. The filters were scraped and washed with 40 ml of phosphate buffered saline (PBS) containing 0.05% TWEEN and then centrifuged at 5000 rpm for 10 min at 4°C. The freeze-thaw cycles cycles were used for DNA extraction. The level of extracted DNA was measured by NanoDrop (Spectrophotometer, ND1000), and PCR prod-ucts were separated by electrophoresis in 2% agarose gel.

    Results

    PCR analysis showed out of the 48 samples, 17 samples (35.4%) werepositive PCR amplification by nested PCR in the case of Cryptosporidium spp. In total, 11 and 6 samples were positive in the winter and summer seasons, respectively. 

    Conclusion

    Local authorities should be aware of probable cryptosporidiosis epidemics between the residents by paying attention to wastewater treatment processes and suitable preventive measures will help reduce the transmission of human and animal cryptosporidiosis.

    Keywords: Cryptosporidium, Wastewater, PCR, Bushehr, The Persian Gulf}
  • Seyed Mehdi Ale-Tayeb, Ehsan Derikvand *, Mohsen Solimani Babarsad, Majid Razaz, Hossein Eslami
    Background
    Electrocoagulation (EC) is a safe method for removing environmental pollutants without the need for additional chemical materials. This study investigates the performance of EC in removing chemical oxygen demand (COD), total organic carbon (TOC), total suspended solids (TSS), and turbidity from drilling waste generated by oil rigs.
    Methods
    An experimental study was performed on a pilot scale in an EC reactor provided from a cylindrical glass cell (height: 30 cm and inner diameter: 5 cm), a pair of aluminum and iron electrodes, a power supply, an aeration system. wastewater Samples were collected from one of the drilling rigs in Khuzestan. The effect of current density, operation time and pH parameters on removal of COD, TOC, TSS and turbidity were determined and the optimal values of the parameters were determined.
    Results
    It was found that system voltage, operation time and pH values on the removal efficiency of pollutants were statistically significant at the 0.01 level. The optimum values of pH, current density and operation time were obtained 7, 20 mA/cm2 and 60 minutes, respectively and the removal efficiencies of COD, TOC, TSS and turbidity under the optimum conditions were 72%, 79%, 67% and 63%, respectively. Also, the consumption of energy was estimated to be 8.4 kWh/m3.
    Conclusion
    The results indicated that the EC process is a cost-effective method in removing pollutants caused by drilling of oil rigs and its efficiency can be improved by applying optimal conditions such as current density and pH.
    Keywords: Electrocoagulation, Chemical Oxygen demand, Environmental pollution, Wastewater}
  • سید مهدی میریان، افشین ابراهیمی*
    مقدمه

    هدف از انجام پژوهش حاضر، مدل سازی یک تصفیه خانه فاضلاب واقعی در حال بهره برداری با استفاده از نرم افزار GPS-X بود. بدین ترتیب، نتایج خروجی نرم افزار با نتایج آزمایش های پساب تصفیه خانه فاضلاب مورد نظر صحت سنجی شد. سپس نرخ لجن برگشتی، لجن بازچرخش شده و لجن دفع شده تصفیه خانه فاضلاب به روش Modified Ludzack-Ettinger (MLE) بهینه سازی گردید؛ به صورتی که بیشترین تاثیر را روی کیفیت پساب خروجی به خصوص شاخص های Chemical oxygen demand (COD) و نیترات داشته باشد.

    روش ها

    ابتدا با استفاده از داده های موجود تصفیه خانه فاضلاب مورد نظر، فرایندهای آن در نرم افزار مدل شد و انطباق مدل با تصفیه خانه موجود بررسی گردید. بعد از صحت سنجی نرم افزار، به منظور بررسی شاخص های موثر بر فرایند لجن فعال شامل نرخ لجن برگشتی، نرخ لجن مازاد و نرخ لجن بازچرخش داخلی در تصفیه مواد آلی و نیتروژن، شاخص های COD، نیترات و آمونیاک به عنوان شاخص سنجش آلودگی مورد بررسی قرار گرفت. همچنین، فرایند MLE جهت حذف نیتروژن در نرم افزار مدل سازی شد. سپس با تغییر شاخص ها و بررسی خروجی های به دست آمده، نتایج در خصوص اثر افزایش نرخ بازچرخش لجن در غلظت COD در پساب خروجی و اثر افزایش و کاهش نرخ بازچرخش داخلی و نرخ لجن دفعی در حذف COD بررسی گردید. همچنین، اثر متقابل تغییرات بازچرخانی داخلی لجن و لجن برگشتی و مقدار لجن مازاد دفعی بر حذف نیترات به وسیله نمودارهای مختلف نشان داده شد.

    یافته ها

    ضمن صحت سنجی نرم افزار در مطالعه حاضر، نتایج حاصل از طراحی آزمایش نشان داد که نرخ لجن برگشتی و بازچرخش داخلی دارای اثرات متقابل نسبت به یکدیگر در حذف COD و نیترات بودند و در حالت بهینه بهره برداری و طراحی، نسبت 54/0 برای لجن برگشتی و یک برابر بازچرخانی داخلی و نسبت 021/0 برای لجن دفعی، بیشترین تاثیر را بر راندمان حدف COD و نیترات و افزایش کیفیت پساب خروجی داشت.

    نتیجه گیری

    استفاده از نرم افزار GPS-X می تواند در مدل سازی و بهینه سازی فرایندهای تصفیه فاضلاب مورد استفاده قرار گیرد.

    کلید واژگان: فاضلاب, لجن, بازچرخش لجن, اکسیژن مورد نیاز شیمیایی, نیترات}
    Seyed Mahdy Mirian, Afshin Ebrahmi*
    Background

    The purpose of this study was to model a real wastewater treatment plant in operation with GPS-X software. In the following, the verification of the output results of the software was done with the results of the effluent tests of the discussed sewage treatment plant. Then, the rate of return sludge, recycled sludge, and disposed sludge of the wastewater treatment plant was optimized by Modified Ludzack-Ettinger (MLE) method, so that it has the greatest effect on the quality of the effluent, especially chemical oxygen demand (COD) and nitrate (NO3) parameters.

    Methods

    First, using the available data of an operating wastewater treatment plant, the processes of the treatment plant were modeled in the software and the compatibility of the model with the existing treatment plant was checked. After the validation of the software, in order to check the parameters affecting the activated sludge process, including return sludge rate, excess sludge rate, and internal recirculation sludge rate in the treatment of organic matter and nitrogen, COD, NO3, and ammonia parameters were investigated as indicators of pollution. In addition, the MLE process for nitrogen removal was modeled in the software. After performing the modeling by changing the parameters and checking the resulting outputs, the results regarding the effect of increasing the sludge recirculation rate on the COD concentration in the effluent and the effect of increasing and decreasing the internal recirculation rate and the disposal sludge rate on COD removal were examined. In addition, the mutual effect of changes in internal sludge recycling and return sludge and the amount of excess sludge disposal on NO3 removal was shown by different graphs.

    Findings

    In this study, while validating the software, the results of the experiment design showed that the return sludge rate and the internal recirculation rate had mutual effects on each other in the removal of COD and NO3, and in the optimal mode of operation and design, the ratio of 0.54 for return sludge and one-time internal recycling and ratio of 0.021 for disposal sludge had the greatest effect on COD and NO3 removal target efficiency and increasing the effluent quality.

    Conclusion

    GPS-X software can be used in the modeling and optimization of wastewater treatment processes.

    Keywords: Wastewater, Sludge, Sludge recirculation, COD, Nitrates}
  • MohammadReza Khaksar, Yadollah Ghafuri *, AhmadReza Yari
    Background

     The presence of anticancer drugs in water sources has become critical in recent years. Anticancer drugs are used in controlled amounts and conditions in medical centers. Cancerostatic platinum complexes (CPC) like cisplatin, carboplatin, and oxaliplatin are used in oncology centers to treat many cancers.

    Objectives

     We determined the environmental risk of these compounds in municipal wastewater effluent of Qom, Iran.

    Methods

     The LC-MS/MS technique quantified platinum complex drugs in wastewater effluent. Based on the blank laboratory method, the limit of detection (LOD) was determined as 0.009 µg/L, 0.013 µg/L, and 0.017 µg/L for oxaliplatin, carboplatin, and cisplatin, respectively.

    Results

     The cisplatin, carboplatin, and oxaliplatin concentrations in wastewater effluent were 0.19 ± 0.098, 0.22 ± 0.094, and 0.12 ± 0.059 µg/L, respectively. Ecological risk assessment results indicated that RQsw for cisplatin, carboplatin, and oxaliplatin was 0.017, 0.013, and 0.02, respectively, showing that the platinum complex drugs had insignificant ecological exposure risk. Furthermore, ΣRQsw was estimated at < 1.

    Conclusions

     Managing cytotoxic waste from hospital oncology wards is vital for environmental pollution control. The use of other methods to remove these compounds, such as advanced oxidation processes and membrane systems, is inevitable.

    Keywords: Risk, Toxicity, Platinum Compounds, Wastewater, Qom}
  • Haider Kamel Alzaidy*, Firas Mustafa Al Khatib, Ammar Salman Dawood
    Background

    Petroleum hydrocarbons that are released from industrial processes cause damage to aquatic life and degrade ecosystems by accumulating in the food chain, allowing living organisms to produce toxic secretions.

    Methods

    In this study, a pumice stone was used to remove total petroleum hydrocarbons (TPHs) from industrial wastewater in the south refinery company in Iraq/Basrah by coagulation and flocculation processes using the design of experiments (DOE) approach using the method of analyzing screening designs and measurement of the samples using GC instrument.

    Results

    The maximum removal was 99% at pH 3, coagulation dose of 0.5 g, and time of 60 min, and a comparison was made between the DOE and the multiple linear regression (MLR) to determine the effectiveness of the system used, which proved its incredible effectiveness.

    Conclusion

    According to the results, a great convergence between the actual and prediction results of removal was found, while MLR was very far from the actual and predicted removal results. The high efficiency of pumice stone was found in removing petroleum hydrocarbons from the industrial wastewater of the South Refineries Company. Pumice stone is widely available in the market and cheap economically.

    Keywords: Pumice, Wastewater, Hydrocarbons, Flocculation, coagulation, Petroleum}
  • Somayeh Rahimi, Farzaneh Mohammadi*, Soudabeh Ghodsi, Maryam Mohammadi, Hossein Karimi
    Background

    Recently, sulfate radical-based photocatalytic processes have attracted significant interests because of unique advantages in pollutants purification. In this study, TiO2-Fe3O4 nanocomposites in the presence of persulfate and under ultraviolet light-emitting diode (UV-LED) irradiation were applied for reactive red 198 removal with a focus on the main operating parameters such as pH, persulfate molar concentration, irradiation time, and catalyst dosages in different initial concentrations.

    Methods

    The nanoparticles were synthesized by co-precipitation technique. The X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) coupled with energy dispersive X-ray (EDX) and Fourier transform infrared spectroscopy (FTIR) analysis were used to evaluate TiO2- Fe3O4 nanocomposites. The response surface methodology (RSM) was employed for modeling and optimization. The kinetics and mechanisms of decolorization by sulfate and hydroxyl radicals were investigated. The mineralization of dye was evaluated using total organic carbon (TOC) analysis.

    Results

    Modeling and optimization through RSM showed that the maximum decolorization of reactive red 198 is accursed an initial concentration of 10-50 mg/L was reached under UV-LED irradiation of 62-85 min, persulfate concentration = 0.8-1 mM, 0.19-0.3 g/L TiO2-Fe3O4 nanocomposites concentration, and pH = 3. The kinetics of process was in agreement with pseudo-first order. The mineralization of reactive red 198 during the optimum conditions was determined at about 61.1% and 49.6%, meanwhile, the decolorization efficiency in the same conditions was approximately 98.1% and 87.6%, respectively.

    Conclusion

    The use of TiO2-Fe3O4 nanocomposites under UV-LED irradiation in the presence of persulfate can be used as an efficient and promising method for dye removal from textile wastewater.

    Keywords: Reactive red 198, Nanocomposites, Titanium dioxide, Wastewater}
  • Md. Shakir Ahmed *, Md. Rafiquzzaman
    Textile is one of the biggest industries and it has an enormous impact on the global economy. However, the textile industry is labelled as the most polluting of all the industries and this is due to its contaminated wastewater. Textile wastewater contains organic hazardous compounds like alkylphenols (APs) such as nonylphenols (NPs), and alkylphenol ethoxylates (APEOs) for example nonylphenol ethoxylates (NPEOs), which may come from various detergents, wetting agents, emulsifying agents, etc. used in textile industries.  Literature review revealed that no work was reported on the APs and APEOs in the textile wastewater of Bangladesh. This study reports the status of some APs and some APEOs after assessing wastewater of some textile industries in Dhaka, Bangladesh. Investigations were carried out with the wastewater of seven textile industries located in the Dhaka Division, Bangladesh. Tests were carried out by an Agilent Liquid Chromatography-Mass Spectrometer (LC-MS). The results revealed that none of the wastewater samples contained APs, and APEOs other than nonylphenol ethoxylates (NPEOs) a form of APEOs. And it might have released from the textile products treating stuff through dissolution process. Among all the seven industries, two industries (28%) contained nonylphenol ethoxylates (NPEOs). The mean concentrations of the detected NPEOs were determined as 11.27 ± 0.24 µg L-1 and 14.01 ± 0.09 µg L-1 in the wastewater of the mentioned two industries. The levels of the observed concentrations of NPEOs were much higher than the specified limits for textile wastewater. Findings of the present work will create pressure on the textile industries of home and abroad for treating textile wastewater effectively and not letting APEOs cum NPEOs in the wastewater. And such activities all over will pave the way to save the ecological system.
    Keywords: wastewater, Organic compounds, Alkylphenols, Nonylphenols, Alkylphenol Ethoxylates, Nonylphenol Ethoxylates, LC-MS}
نکته
  • نتایج بر اساس تاریخ انتشار مرتب شده‌اند.
  • کلیدواژه مورد نظر شما تنها در فیلد کلیدواژگان مقالات جستجو شده‌است. به منظور حذف نتایج غیر مرتبط، جستجو تنها در مقالات مجلاتی انجام شده که با مجله ماخذ هم موضوع هستند.
  • در صورتی که می‌خواهید جستجو را در همه موضوعات و با شرایط دیگر تکرار کنید به صفحه جستجوی پیشرفته مجلات مراجعه کنید.
درخواست پشتیبانی - گزارش اشکال