Chromium removal and water recycling from electroplating wastewater through direct osmosis: Modeling and optimization by response surface methodology

Considering the carcinogenic effects of heavy metals, such as chromium, it is essential to remove these elements from water and wastewater. Direct osmosis is a new membrane technology, which can be a proper alternative to conventional chromium removal processes. The wastewater samples were collected from an electroplating unit, located in Alborz industrial city, Qazvin, Iran. Magnesium chloride was used as the draw solution, and a semipermeable membrane (Aquaporin) was used in this study. The experiments were designed, using response surface methodology (RSM) and central composite design (CCD) with draw solution concentration (0.5- 1.5 M), feed solution concentration (4-12 mg/L), and experiment time (30-90 minutes) as variable factors. The chromium concentration and water flux were also measured, based on atomic absorption spectrophotometry and water flux equation, respectively. Direct osmosis was highly efficient in chromium removal and water recycling. Water flux and chromium removal efficiency were 15.6 LMH and 85.58%, respectively, under optimal conditions (draw solution = 1.27 mol/L, feed solution = 4 mg/L, and experiment time = 90 min). In terms of validity, the results predicted by the quadratic polynomial model were in good agreement with the responses reported in the laboratory. In direct osmosis, the use of magnesium chloride as the draw solution resulted in the acceptable chromium removal from electroplating wastewater. Using this method, chromium concentration in wastewater reduced to a level lower than the discharge standards, established by Iran’s Department of Environment.