Preparation and characterization of Ti (BH4) 3 (THF) 3 and V (BH4) 2 (TMEDA) 2 complexes

Author(s):

Aghabozorgh. , Alizadeh , R

Abstract:
We have recently synthesized Ti(BH4)3 (THF)3 and V(BH4)2(TMEDA)2complexes. The reaction of TiCl3(THF)3 with NaBH4 in dry THF gave flat blue crystals, Ti(BH4)3 (THF)3. The reaction of VCl3 with NaBH4 in presence of N, N,, – tetramethylethylenediamine, TMEDA, produced violet crystal, V(BH4)2(TMEDA)2. Vibrational and magnetic properties of Ti(BH4)3 (THF)3 and V(BH4)2(TMEDA)2 have been studied.
Language:
English
Published:
Iranian Journal of Chemistry and Chemical Engineering, Volume:13 Issue: 2, Nov-Dec 1994
Page:
68
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