Pollution
Volume:2 Issue: 2, Spring 2016

The surface water chemistry of Thiruvananthapuram Museum Lake was carried out in the period of February 2013 to January 2014. Correlation study of the parameters and overall CCME WQI (Canadian Council of Ministers of the Environment Water quality Index) was also prepared in the study for the lake water. The parameters analysed are cations such as Ca2, Na, Mg2 and K and the anions like PO4-, Si4- , NO3- and NO2-. Abiotic factors like water pH, Temperature, Conductivity, TDS, Total Alkalinity and Total Hardness were also analysed. The pH ranged between 6.5 to 7.4. The total hardness ranged between 50.8-99 mg/L which shows the water is moderately hard one. During the pre monsoon period, water temperature showed a positive correlation with total alkalinity (r= 0.915) pH (r= 0.841) and TDS (0.876). Dissolved Oxygen (DO) value showed a positive correlation with Biological Oxygen Demand (BOD) (r= 0.999). The overall CCME water quality index was 80.81 which indicate the water body is protected with only a minor degree of threats. The quality of the water is an essential element of the Thiruvananthapuram Zoo environment with respect to both healths of the ecosystem and zoo tourism enjoyment. Moreover, if maintained properly, this water body can be treated as a major drinking water source for the zoo animals.

Groundwater aquifers are an important source of water supply for agriculture, industry and drinking. The present study investigates the changes in the quality of groundwater using geostatistical methods in the Ravar plain during a 10-year period. In this study, after selecting the appropriate spatial interpolation method to draw water quality parameters such as TDS, SAR and EC, zoning maps of Ravar plain were provided for three periods of time: the first period (2002-2005), an intermediate period (2006-2009) and the final period (2010-2012) in two seasons using ArcGIS 10.1. For this purpose, data were evaluated in GS 5.1 software, after calculation, the best model with the lowest estimated error was selected for zoning water quality parameters. Because of the lowest estimation error, Kriging, Gaussian and Spherical variogram models were selected as appropriate interpolation method for zoning the quality parameters. The results of the spatial analysis of TDS showed that TDS have been increased in the study area. Due to the amount of dissolved solids, EC amount was highly variable. According to the Wilcox classification, at the end of the period, water quality of agricultural was inappropriate in most of the area which represents the increase of electrical conductivity during the period.

This study investigated the occurrence and removal of 12 antibiotics (ciprofloxacin, enrofloxacin, levofloxacin, norfloxacin, nalidixic acid, azithromycin, clarithromycin, roxithromycin, lincomycin, novobiocin, sulfamethoxazole, trimethoprim) at four sewage treatment plants (STPs): two STPs in Kyoto, Japan and two STPs in Beijing, China. The STPs differed in design and operation conditions, utilized a variety of secondary treatment processes. The antibiotics were frequently detected in influents and effluents, and ranged from ng/L up to lower μg/L. In influent, clarithromycin (1.1–1.6 μg/L) and levofloxacin (3.6–6.8 μg/L) were detected in the highest concentration in Japanese and Chinese STPs, respectively. The overall elimination of the antibiotics were differed between STPs and ranged from negative to >90%. These data demonstrate that there are detectable levels of antibiotics are discharging from STPs, and only some of these antibiotics are being removed in a significant proportion by STPs. It was also observed that biological nutrient removal based sewage treatment processes (anaerobic–anoxic–oxic: A2O; and anoxic–oxic: AO) have relatively higher antibiotics removal efficiencies than oxidation ditch (OD) processes.

Identifying Municipal Solid Waste (MSW) disposal sites and appropriately managing them is a challenging task to many developing countries like Bangladesh. It is a complex issue in an urban area, as increasing population levels, rapid economic growth and rise in community living standard, accelerates the generation rate of MSW. The study area is zone-2 (Mirpur-Pallabi) of Dhaka North City Corporation (DNCC) (10.40 km2) is a residential area, from where about 353.34 ton/day solid waste is generated and among them about 57.43% were managed by DNCC. There are 41 different size containers present at 17 locations in study area. The existing site and waste collecting containers are not sufficient, which deteriorates the environment due to illegal waste dumping and about 15 illegal dumping sites were identified. To identify proper waste dumping site and prevent contamination, Geographical Information System (GIS) was used to propose an efficient scenario with relocating the existing waste collecting containers and another scenario was proposed with number of containers (73) to attain an 93.68% waste collection efficiency including optimization and selection of waste collecting routes for the study area. This study also indicate that the application of GIS is an efficient and low cost tool to study and select appropriate dumping site so as to facilitate decision making processes.

The present study has been undertaken in a laboratory scale to characterize and investigate pollution potential of textile effluents from DEPZ area in Dhaka, Bangladesh. Collected effluent samples from five different industries were analyzed for physico-chemical parameters using field kits and Standard Methods, and for metals using Flame Atomic Absorption Spectrophotometer (FAAS). The average physico-chemical parameters such as temperature, color, pH, DO, EC, BOD, COD, TS, total alkalinity and total hardness were found 52.4 ºC, 2646 PCU, 9.788, 1.492 mg/L, 7473.2 μS/cm, 157 mg/L, 508.8 mg/L, 9140.8 mg/L, 761.2 mg/L and 189.6 mg/L, respectively. The average concentrations of metal found in the textile effluents were in the order of Na (4611.762 mg/L) > Ca (9.166 mg/L) > Mg (3.578 mg/L) > Zn (0.113 mg/L) > Ni (0.0074 mg/L) > Cu (0.0032 mg/L). All the measured physico-chemical parameter values are negatively deviated but metal concentrations (except Na) are positively deviated from standard limits of wastewater discharge set by Department of Environment and US Environmental Protection Agency. In view of those characteristics, the textile industry effluents should be considered to be treated by setting eco-friendly effluent treatment plant (ETP) before directly discharging into the water bodies.

Today, ecotourism is a major tourist activity around the world. It is based on environment potential through which suitable utilization and conservation of sites under management practices including considering accurate planning, potential, and peoples’ preferences are realized. The present study was conducted to determine people’s recreational preferences using questionnaires to evaluate the ecotourism potentials (recreational activities that choice in questioner by visitors) for site selection and land use planning, and to analyze the functional relationships among zones in the MianKaleh wildlife sanctuary, south of the Caspian Sea in Mazandaran and Golestan Provinces of Iran. Recreational preferences of people were found to be bird watching, swimming, camping, sightseeing, horse riding, and boating. Multi Criteria Evaluation was used to assess the ecotourism potential. For land use planning, the Multi Objective Land Allocation function included environmental suitability maps, zone weighting, and a set of desirable areas for each zone. Post processing functions (filters, zone size, and distance to other zones) and functional relationship diagrams were applied to amend the zoning maps. The functional relationship diagram concept was applied to the amended maps for optimizing access and identifying the relationships among zones. Overall, the results revealed that MCE and MOLA methods are capable of evaluating and zoning the wildlife sanctuary. Furthermore, post-processing and functional relationship diagrams were effective in selecting recreational sites. The results of this research revealed the recreational potential of MianKaleh wildlife sanctuary. Land planning for ecotourism can now be implemented using the results of this study that will upgrade the conservation status in the area.

Batiaghata Upazila, Khulna District in south-west coastal region of Bangladesh is the mostly saline affected area, where agriculture activities are mainly dependent on rainfall. 23 water samples from surface water and shallow tube well (STW) were collected in the monsoon season and analyzed for physico-chemical properties to classify them according to salinity hazard. Electrical Conductivity (EC) of both surface and groundwater samples were slightly higher than that of acceptable limit ( Ca2 > Mg2 > K in both surface and groundwater while the anions trend in both surface and groundwater of the study area were Cl¯ > SO42¯ > PO43¯. EC and TDS showed high positive correlation with Na, K and Ca2 with Cl¯ as confirmed from Correlation Matrix and Principal Component Analysis (PCA). Most of the STW water samples compared to the surface water had higher Soluble Sodium Percentage (SSP) values while Sodium Adsorption Ratio (SAR) indicated the surface water and ground water with low sodium hazard. The Kelly’s ratio of STW water is more subjected to sodium hazard compared to surface water in the study area.

The resource intensive human activities (such as mining and extraction of mineral oils for betterment of life and modernization of society) have increased environmental pollution several folds. Products of mining and petrochemical industries are advantageous for the modern society. But waste generated such as BTEX from such industries are carcinogenic, toxic and causes adverse effects on environment and human health. These wastes are classified as hazardous waste which cannot be used further. Pollution of soil-water interface due to the release of hydrocarbons in environment is a major public health concern, and therefore, remediation of these pollutants is needed to reduce risk to human and environment. Various methods such as biological, chemical and physical method are used to degrade these pollutants from wastewater. In the present works photochemical degradation of toluene and benzene in wastewater are studied using activated Carbon−TiO2 composites as catalysts in the presence of UV irradiation in photochemical reactor. Composites are prepared by sol-gel method and further characterized by X-ray diffractometry (XRD), scanning electron microscope (SEM) and Fourier transformed-Infrared spectroscopy (FT-IR). The Photocatalytic efficiencies of the synthesized composites were determined by the mineralization of toluene and benzene under UV irradiation in photochemical reactor.

The adsorption study was conducted on three Japanese soils with different soil properties to characterize the adsorption pattern of Arsenic (As). Double tube method was used to find out the effect of soil moisture levels on As adsorption. For this study, besides double tube method, conventional batch method also was used. The As adsorption showed two phase kinetics. An initial and rapid adsorption was found at first hour and then gradually preceded before equilibrium in all the three soils in the case of double tube method and in clay loam and light clay soil in the case of batch method. Adsorption seemed to reach equilibrium at 24 h in both methods, though the initial adsorbate load was not the same at the same applied concentration in the methods. Adsorption activity differed according to soil and as well as to the methods. The highest adsorption was found in clay loam soil followed by light clay and sandy loam soil. The linear model of Freundlich adsorption was found better fitted in the case of double tube method than batch method. Suggesting that, under the experimental conditions stated here, the double tube method is more appropriate to describe the adsorption of As in the three Japanese soils under normal field condition. The concentration of As in soil water was slightly increased at different moisture levels from 50%-80% which may contribute significantly to the bioavailability of As at the moisture level below maximum filed capacity.

Bioremoval and bioreduction activities of hydrocarbon (diesel) isolation from environmental samples were studied by the activity of biosurfactant production, and calculating emulsification index, gravimetric, and FTIR analysis along with the estimation of bacterial biomass. Sample from soil near petrol, diesel pumps and water sample from Thesjaswini River near Padannakad, Kasaragod, Kerala, India, were used to screen the potential diesel oil utilizing bacteria. Among the bacterial isolates (Staphylococcus, Bacillus and Corynebacterium strains), Staphylococcus sp was the potent degraders of diesel oil. Staphylococcus strain was observed to be maximum diesel oil utilizing ability (73% emulsification index) and change in the functional groups of the compound (FTIR analysis). The strain showed optimal growth at 37oC with pH 7, agitation of 150 rpm and time period (5days). The results revealed the possibility to use these strain for the reduction of complex hydrocarbon in ecosystems where they accumulate and cause pollution problems. The highest rate of hydrocarbon degradation occurred when the bacterial strain is a biosurfactants producer. The selective strain produces biosurfactants which increase the interfacial area for contact to give improved uptake of hydrophobic substrates. Bacterial strains capable of degrading complex hydrocarbons, present in the environment, have a potential to be used as an effective tool for removing ecotoxic compounds. Furthermore, results indicated that the bacterial strain Staphylococcus sp could be potentially used in biodegradation of diesel oil in waste water and had a promising application in bioremediation of hydrocarbon contaminated environments.