نشریه پژوهش های کاربردی مهندسی شیمی - پلیمر
سال دوم شماره 1 (پیاپی 3، بهار 1397)

In human-made materials, aerogels have the least thermal conduction coefficient. The least thermal conduction, which aerogels can have, is equivalent to air conduction, about 0.021W/mK. In some applications, lowest conductions is to be needed. In this study, novolac aerogles are used as spacer, for designing and making multilayer super insulators with aluminum foil reflective layers. The performance of these insulators, are extremely depends on density, porosity and the size of pores in aerogel and number of layers in the overall thickness of insulator. In this study, for decreasing effective thermal conduction of multilayer insulations, tow parameters of density of aerogel and ratio of number of layers to thickness of insulator (layer density), are examined in 25 ˚C to 200 ˚C boundary conditions. First, by assessment of aerogel novolac density effect on thermal conduction, aerogel with density of 0.076 g/cm3 was chosen as the best spacer. In the next part, ratio of 25 layer per centimeter of thickness was chosen as the best layer density. Finally, by making multilayer super insulators, based on this results, an insulator with 5×10-4W/mK effective thermal conductivity was obtaind without evacuation of spacer.

One of the problems for use of rubber in various industries is the surface tension at the surface of rubbers, which results in the crack on the surface, fracture of the rubber and reduces its service life. These tensions are caused by contacting the rubber component with the metal surface and the friction between two surfaces. Roughness of the surface, the composition of the rubber compound, the environmental factors, test conditions and etc. affect the friction between rubbers – metal. Surface roughness plays an important role in sliding between two surfaces and mainly controls friction behavior. On the other hand, roughness effect on the coefficient of friction is controllable using a suitable lubricant. In the present study regarding to the application of JP4 as an aviation fuel, the effect of JP4 fuel as a lubricant was investigated in the reduction of the sliding friction coefficient between the NBR and aluminum surfaces with different roughness. Experimental studies showed, friction coefficient has a good correlation with the mean surface roughness (Ra). By applying JP4 lubricant, the coefficient of friction decreased by about 75%. JP4 fuel as lubricant has changed the trend of varying friction coefficient from decreasing to increasing regard to the surface roughness.

Ganoderma lucidum is one of the best-known medicinal mushrooms in the world. It contains substantial amounts of intra- and extracellular secondary metabolites and polysaccharides each with its own specific medicinal and medical uses. The chitin-glucan complex (CGC) is considered one of the important polysaccharides of this fungus. Among the 10 various culture media that were studied, the one containing PDB at 24g/l, peptone at 1g/l, and with the dry weight of cells of 11.6 g/l, the produced CGC of 3.2g/l, and with 27.6 percent CGC in the dry weight of the cells was selected as the suitable culture medium. FTIR analysis was performed for characterization of the produced CGC and its antibacterial properties were studied. The obtained time profile for CGC growth and production was 20 days and, using the logistic growth model and the Lodding-Pipet equation, the calculated specific growth rate of Ganoderma lucidum (μm) and the volumetric productivity for the product were 2.85 g CGC L-1day-and 0.5274 day-1, respectively. The calculations indicated there were high degrees of conformance between the model and the laboratory data related to kinetic characteristics of cell growth (R2= 0.9679) and to CGC production (R2=0.9901). Therefore, the introduced kinetic model can serve as an effective guide to control the fermentation process in industrial production of the valuable CGC polymer.

Most scientists are trying to treat cancer, and in this regard were produced numerous anticancer drugs, that adverse effects on non-target tissue. To overcome this, drugs freight to magnetic nanoparticles Chitosan and its carboxymethyl secondary coumpands are biopolymers that are non-toxic, biodegradable therefore found applications in biomedical field. We explain here that glycerol monooleate covered magnetic nanoparticles (GMO-MNPs) capable of transporting hydrophobic anticancer drugs. In the present study, we have expanded 5-fluorouracil (5-FU) that loaded on chitosan MNPs for targeted cancer therapy. The modified nano-adsorbent was then characterized by Fourier Infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), elemental analysis of CHN (9) and thermal weighing analysis (TGA). Lab conditions such as pH, contact time were optimized. To analyze the structure of the sample, X-ray diffraction spectroscopy was used to investigate the magnetic properties of the nanosized particles synthesized by the magnetometer and to detect the phase type formed on the monolayer glycerol matrix network using a polarizing light microscope. Also, the study showed essential oil release in the external environment of 90% for 30 hours. The optimized magnetic nanoparticles according to SEM image, exhibited segregated nanoparticles with sub-spherical smooth morphology and also the high thermal stability of 5-Fluorouracil nanoparticles which indicated a well-established structure of nanoparticles.

Electronic wastes are known as the most important solid wastes in 21th century. They are producing two or three time faster than other solid waste streams. Many researchers studied bioleaching of e-wastes using Acidithiobacillus ferrooxidans. The presence of alkaline metals cause e-wastes show an alkalinity nature. By adding e-wastes to the environment the pH of solution increases sensibly. Many researchers supposed the optimal pH range of A. ferrooxidans which is 1.5-2.5 as the optimal pH range to reach maximum recovery. So in the bioleaching process by daily pH adjusting in the range and using sensible amount of sulfuric acid, control the pH of solution about 2. In this research two same experiments, just the pH of one of them was adjusted daily, were done. In both experiments the environmental situation including pulp density of 15 g/l, inoculum 10% (v/v), the temperature of 30ºC, and shaking rate of 130 rpm was the same. For 25 days Cu recovery, bacterial count, pH, and Eh were examined. The results showed the maximum Cu recovery at the sample without pH adjusting was about 100% but at the sample with pH adjusting recovery was reduced to 90%. The bacterial count diagram showed the bacterium is well active in both experiments. To maximize recovery, reducing acid consumption, and increasing process economy there is no need to adjust the pH of solution.

Rubber to metal adhesion in rubber to metal parts is of great importance. The optimum performance of this type of adhesion depends on the adhesion strength between rubber compound and metal surface and the consolidation of the compound. Resin additives and the presence of silica particles play a different role in adhesion improvement. Peel90 tensile strength and adhesion tests have been used to evaluate the effect of additives. According to the results, the presence of 15 phr of phenol formaldehyde resin has been coused to increase rubber to metal adhesion up to 17% but a reduction of 43% in the tensile strength of compound. On the other hand, it was observed that the presence of 15 phr HMMM resin along with phenol formaldehyde resin not only could improve rubber to metal adhesion up to 137%, but also decreased the loss of tensile strength of the rubber mixture to 12%. This is while the addition of 5 phr aerosol along with these resins could increase the adhesion to 175%. In this state, tensile properties have only drop out 3%.