فهرست مطالب

Environmental Research - Volume:8 Issue: 1, Winter 2014

International Journal Of Environmental Research
Volume:8 Issue: 1, Winter 2014

  • تاریخ انتشار: 1392/09/29
  • تعداد عناوین: 25
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  • C. Fern, Aacute, Ndez, E.J. C., Aacute, Ceres, E.R. Parodi Pages 1-14
    The phytoplankton structure and dynamics were analysed in relation to abiotic variables in Paso de las Piedras Reservoir, Argentina. Phytoplankton driving forces were explored using a functional approach. A total of 15 functional groups were identified among which D, P, H1, F, J and C were the most important. A Canonical variate analysis indicated that the categorization of the species in functional groups and its relationship with the temporal species clustering was not a random result. In the redundancy analysis, temporal ordination dynamics of functional groups was well described by the distribution of samples. Remarkable shifts in composition and biomass of phytoplankton occurred in agreement with changes in temperature, N:P ratio and transparency. The group succession could be summarized as: P/J (early summer)→P/ H1 (late summer)→P (early autumn)→P/F (late autumn)→C (early winter)→D (late winter)→Y (early spring)→D (early spring)→P (late spring). The majority of the associations detected were typical of eutrophichypertrophic systems. With the exception of H1, the groups that most contribute to biovolume were those characteristics of mixed aquatic environments, i. e., non-stratifying lakes or deep, well-mixed epilimnia of stratifying lakes. The diversity indices, in terms of functional groups, were low, meaning that a small number of traits were present and/or that there was an inequitable distribution.
    Keywords: Functional groups, Phytoplankton dynamics, Paso de las Piedras Reservoir, Diversity
  • M. Al Harbi Pages 15-26
    This study assesses the air quality of two urban localities, Fahaheel and Al-Rabia City, to assist local authorities to generate information supporting the planning of pollution control strategies to keep pollutants within safe limits in the long run. In terms of diurnal and seasonal variations, almost all measured pollutants exhibited two peaks: one in the morning and another in the afternoon. These two peaks resulted from numerous activities (schools, open stores, traffic, restaurants and markets, and central heating) practiced in these two cities during associated peaks hours. Nevertheless, there were noteworthy differences in air pollutants’ magnitude (values) between the two cities. There were a number of exceedances of KUEPA air quality threshold values in both urban localities; the highest numbers were in NMHC and the lowest numbers were in O3 and CO. No exceedances were found in SO2 in Al-Rabia City. In an attempt to identify the most probable sources of air pollution, concentration roses were plotted for annual durations for both Fahaheel and Al-Rabia. Furthermore, the Chemical Mass Balance (CMB) model was developed to quantify the contribution of each prevalent source to measured emission concentration. Results show that the main emission sources in Fahaheel were petroleum downstream facilities and highway traffic, which accounted for 69% and 17%, respectively. In Al-Rabia City, highway traffic and the area’s commercial activity accounted for 79% and 13%, respectively.
    Keywords: Air Pollution, Diurnal variations, Monthly variations, Concentration roses, CMB model
  • V. De Giuli, C.M. Pontarollo, M. De Carli, A. Di Bella Pages 27-38
    Current standards for indoor comfort are based on studies of adults, but they also apply to children, even though children differ in terms of metabolic rates, clothing types, activity levels, and preferences in space arrangement. Children are also more sensitive to a range of environmental factors, they are usually unable to interact with their environment, and they accept indoor conditions passively. This study aims to extend research into indoor environmental quality (IEQ) for children by providing analysis, measurements and surveys carried out in an Italian primary school. Continuous monitoring was combined with a detailed spot monitoring campaign, during which pupils completed a questionnaire so that subjective and objective evaluations could be compared. Thermal comfort was also evaluated by comparing pupils’ sensations based on the two most common approaches: the heat balance and adaptive comfort models. Tests revealed that there was no clear, uniform correspondence between subjective response and acoustic and thermal measurements. Children reacted actively to discomfort, suggesting that they should be allowed to interact with their environment. Building acoustics were also measured in order to evaluate the insulating properties of building elements. The following tests were conducted: façade sound insulation, sound insulation of the vertical and horizontal partitions between classrooms, and the impact levels between overlapped classrooms. Reverberation time and background noise were measured in unoccupied, furnished classrooms after school hours. Impulse response and Speech Transmission Index (STI) measurements were also performed in one classroom.
    Keywords: Indoor environment, Schools, Comfort, Survey
  • H. Kargarsharifabad, M. Behshad Shafii, M. Taeibi Rahni, M. Abbaspour Pages 39-48
    The use of solar collectors in combination with heat pipes is rapidly growing in recent years.Heat pipes, as heat transfer components, have undeniable advantages in comparison with other alternatives. The most important advantage is their high rate of heat transfer at minor temperature differences. Although there have been numerous studies on the heat analysis or first thermodynamic analysis of flat plate solar collectors in combination with heat pipes, the exergy analysis of these collectors is needed to be investigated. In this work, energy and exergy analysis of a flat plate solar collector with a heat pipe is conducted theoretically. Next, the exergy efficiency of pulsating heat pipe flat plate solar collectors (PHPFPSC) is compared with conventional collectors by using the experimental data. The results indicate that the use of heat pipes for heat transfer from the absorption plate to the water reservoir has significantly higher availability and exergy efficiency than the case with conventional collectors with intermediate fluid.
    Keywords: olar Collector, Heat Pipe, Pulsating Heat Pipe (PHP), Exergy Analysis, Exergy Efficiency
  • S.K. Singh, A.K. Ghosh, A. Kumar, K. Kislay, C. Kumar, R.R. Tiwari, R. Parwez, N. Kumar Imam Pages 49-60
    The extent of groundwater arsenic (As) contamination and associated health-risks were studied in the four villages: Chaukia and Terahrasiya (Vaishali); Mamalkha and Masharu (Bhagalpur) in Bihar, India. Groundwater samples were tested using the standard Silverdiethyledithiocarbamate method at 520nm by Thermo UV-1 spectrophotometer. The As levels in both the districts exceeded the WHO standard of 10μg/L for drinking water with a maximum value of 20μg/L in Vaishali and 143μg/L in Bhagalpur. However, the FAO standard of 100μg/L of As for irrigation water was only exceeded in Bhagalpur. The calculated range of the hazard index (HI) for Vaishali was 0.9 to 10, and for Bhagalpur was 10.40 to 40.47. Both ranges exceed the accepted normal toxic HI of 1.00. The cancer risk was derived as 1-5/1000 people to 5 16/10,000 people in Vaishali, and 7-21/1000 and 5-16/1000 people in Bhagalpur. Prevalence of skin pigmentation was double in Vaishali in comparison to Bhagalpur. The analysis of principal components showed that only two components had a fundamental role in defining variance for cancer risk assessment. A more extensive screening of As contamination of groundwater and a follow-up clinical study are necessary to accurately assess the likelihood of As-related cancers in these districts.
    Keywords: Arsenic, Cancer Risk, Diseases, Vaishali, Bhagalpur, Bihar
  • A.M. Mart, Iacute, Nez-Gra, Ntildea., J.L. Goy, C. Zazo Pages 61-68
    This paper presents a mapping procedure for risk mapping of water and wind erosion, which helps to identify protective measures needed in the planning and management of natural parks. The map of water erosion risk was developed by combining the original and revised universal soil loss equation methodologies (USLE-RUSLE), and the map of wind erosion risk was developed using Quirantes’ method. Using GIS techniques allows parametric characterisation of the factors involved in the processes of soil degradation. The validation procedure was carried out in two natural parks in the Spanish Central System. Integration of the two maps resulted in a risk map of water and wind erosion. This mapping shows a high risk of water erosion in areas of high slopes and elevations with little agricultural activity and undulating reliefs. The risk of wind erosion is lower in sectors with analytical and textural high erodibility and low vegetation cover.
    Keywords: Water, wind erosion, Risk mapping, GIS, Environmental planning, Natural parks
  • P.K. Dinesh Kumar, K.R. Naveen Kumar, K.R. Muraleedharanan Pages 69-78
    Behaviour of the dilution characteristics of the coastal waters off Tuticorin is presented in the background of setting up of a desalination plant. Simulations of dispersion and spreading of the proposed discharges has been carried out. Scenarios of dilutions were assessed based on the results of a 2D model using the advection-dispersion theory. It is observed that under prevailing currents in the region, the dispersion of the discharge will be advected away as a combined plume. Ambient conditions are found achieved in close proximity zones within the discharge location and thus there will not be any changes in the water quality in the adjacent coastal waters. Model validation results showed that the values are well in agreement with the observed values. It is suggested that the offshore waters at a distance of 2 Km away from the coastline could be considered as optimum where the environmental impact on the ecosystem due to the disposal operations is considered to be minimum.
    Keywords: Salinity, Desalination plant, Site selection, Model simulation, India
  • K.P.K. Jayakody, T. Shimaoka, T. Komiya, P. Ehler Pages 79-84
    To examine how water retention characteristics in a landfill environment change as a result of solid waste settlement and to derive the evolution of pore size distribution, a lab scale long column experiment was carried out at two different time periods while keeping all the other characteristics constant. Two columns, Column 1 and Column 2, were used in the study. The log normal distribution model was applied to model the experiment data. The Column 1 was used to obtain the water retention curve at time 0 day and the Column 2 at time 180 day. During the experiment period, landfill settlement was mainly in the primary stage of settlement. Pore size distribution was obtained by assuming that the capillary theory is applicable in the landfill environment. The results showed that water retention characteristics in solid waste landfill environment is varied with time and influenced by landfill settlement due to the changes in pore spaces. The obtained results will be taken into consideration when simulating unsaturated leachate and gas flow in municipal solid waste landfill environment.
    Keywords: Municipal solid waste, Landfill, Settlement, Water retention curve, Pore size distribution
  • F.A. Boyaghchi Pages 85-92
    In this research, energetic andexergetic analysis of calcium oxide formation, CO2 emissions, and environmental effects during the clinker production process in rotary kilnare investigated. First the energy and exergy analysis of rotary kiln were carried out according to the first and second law of thermodynamics based on dead state, respectively. Consequently, the amount of CO2 emissions associated with calcination and fuel combustion processes, improvement potential and sustainability index are determined. In this system, the energy efficiency is calculated to be higher than the exergy efficiency, e.g. 53.4% and 28.6% for the energy and exergy efficiencies. The exergy destruction due to irreversible calcination and fuel combustion processes is determined 33,884 kW which is 40.6% of inlet exergy. Results also shows that 18.4% of exergy input is lost by exhaust hotgases.Thetotalemissions are estimated 157,228 kg/hr, which 31.3 % of it isdue tocalcination and 0.9 % of it is due to fuel combustion. The improvement potential (IP) and sustainability index (SI) are calculated 24,193.176 kWand 1.4, respectively.
    Keywords: Energy, Exergy, Efficiency, Greenhouse Gas
  • A. Bartkowiak, J. Lemanowicz Pages 93-100
    To determine the extent and the size of the environment pollution with heavy metals, biological methods, investigating the enzymatic activity of soil can be applied. Most frequently, the enzymes investigated in the soils threatened with anthropogenic contamination are phosphatases, dehydrogenases as reacting fastest to the increase in the content of heavy metals in the environment. The aim of the paper was to apply the results of the research to the activity of selected oxydo-reducing and hydrolytic enzymes to define the pollution of soils with zinc, copper and nickel of the Unisław Basin, the Kujawy and Pomorze Province. The total contents of Cu, Zn and Ni in the soils of the region allow for classifying the soils as unpolluted with those metals, while the contents of the forms extracted with the DTPA solution point to a low mobility of the elements and to their availability to plants. In terms of the negative effect of those heavy metals on the activity of selected enzymes, they have been ordered as follows: dehydrogenases: Ni>Zn, alkaline phosphatase: Zn>Cu, acid phosphatase: Zn>Cu. The use of enzymatic tests to evaluate the ecochemical condition of soils even with a natural content of heavy metals facilitates the long-term monitoring and identifying the trends.
    Keywords: Soil, Heavy metals, Dehydrogenases, Catalase, Phosphatases
  • M. Kolahi, T. Sakai, K. Moriya, M. Yoshikawa, R. Esmaili Pages 101-114
    The proposition that natural areas need protection from the destructive actions of people is widely accepted. This paper examines Iran’s e-society attitudes and capital towards biodiversity conservation and evaluates economically Iran’s national parks (NPs). 2,121 respondents answered an online questionnaire conducted in summer 2012. The majority of respondents had visited one of Iran’s NPs. Almost all respondents were willing to voluntarily participate in conservation and environmental projects; willing to pay for protection; willing to increase the protected areas; willing to visit the NPs in the future; and they were mostly young. There is a resurgent interest in conservation amongst Iranian citizen scientists. Respondents showed that they could collaborate for resource management. They think ecological problems and solutions are human problems and not simply biological problems. Biodiversity conservation in Iran has been threatened by mismanagement, lack of funds, park-other organization conflict, lack of biodiversity awareness, and lack of public participation. Conservation biologists can help engage Iran’s society in conservation efforts by striving to achieve three goals: adjusting the public’s perception of biodiversity, increasing public participation in biodiversity conservation, and encouraging ecotourism by tour packages to develop conservation and local. Furthermore, the government should see the human and environmental condition as one intricate system. The governor must focus on conservation projects that engage the urban populace and support the goal of developing a biodiversity ethic. It should consider updating management, enhancing environmental educational programs, designing environmental volunteer plans, treating ecotourism tour packages, installing real collaborative principles, and establishing co-management and community-based conservation.
    Keywords: National Park, Ecotourism, Willingness to Pay, E, society, Co, management
  • L. Salvati, A. Mavrakis Pages 115-122
    The present study illustrates the long-term changes in selected socioeconomic variables (population, industrial activities, settlement dispersion, and land-use) together with climate aridity trends in Thriasio, the larger industrial area of Greece located twenty kilometers far from Athens. This region, originally devoted to agriculture, experienced fast industrial and economic development during the early 1990s coupled with growing population. According to statistical data covering the period between 1848 and 2011, human pressure increased rapidly in the area determining drastic changes in land-use. The analysis of climate regimes based on meteorological data collected between 1958 and 2010 also indicate a tendency towards aridity possibly contributing to air pollution, soil degradation and desertification. Without a sustainable land management strategy changes in bio-physical and socioeconomic variables are altering irreversibly the fragile ecological equilibrium leading to ecosystem degradation in a highlypopulated area since millennia.
    Keywords: Population, Economic growth, Climate aridity, Mediterranean region, Regional planning
  • N. Oropeza-Garcia, R. Hausler, M. Glaus, R. Vega-Azamar, R. Romero-Lopez Pages 123-132
    In vascular plants, the soil solution is transported from the roots to the leaves through small diameter vessels found in the xylem; this transport not only allows the nutrient uptake but also the accumulation of heavy metals in their shoots. By analogy to this phenomenon, the present study aimed at the evaluation of heavy metals transport (Pb, Cr, As, Cd, Zn, Ni and Al) in pH 4 and pH 8 solutions using a capillary siphon consisting of small pore diameter materials. Determination of the metal concentration in the solutions was performed by means of Inductively Coupled Plasma. The largest transport of metal ions is produced at pH 4, on ascending order, Cr Keywords: Capillary transport, Heavy metals, Small pore diameter materials, Soil solution, Hyperaccumulator plants
  • P. Manju, P.S. Nair Akhil, C.H. Sujatha Pages 133-138
    This article present the result from a study of two sediment cores collected from the environmentally distinct zones of CES. Accumulation status of five toxic metals: Cadmium (Cd), Chromium (Cr), Cobalt (Co), Copper (Cu) and Lead (Pb) were analyzed. Besides texture and CHNS were determined to understand the composition of the sediment. Enrichment Factor (EF) and Anthropogenic Factor (AF) were used to differentiate the typical metal sources. Metal enrichment in the cores revealed heavy load at the northern (NS1) region compared with the southern zone (SS1). Elevation of metal content in core NS1 showed the industrial input. Statistical analyses were employed to understand the origin of metals in the sediment samples. Principal Component Analysis (PCA) distinguishes the two zones with different metal accumulation capacity: highest at NS1 and lowest at SS1. Correlation analysis revealed positive significant relation only in core NS1, adhering to the exposition of the intensified industrial pollution.
    Keywords: Toxic metal, Core sediment, CES, Enrichment Factor, Anthropogenic Factor
  • M.A. Abdoli, F. Mohamadi, B. Ghobadian, E. Fayyazi Pages 139-148
    Using low-cost feedstocks such as rendered animal fats in biodiesel production willreducebiodieselexpenditures. One of the low-cost feedstocksfor biodiesel production could be the fat extracted from poultry feathers producedin slaughterhouses abundantly. This paper describes a new and environmentally friendly process for developing biodiesel production technology from feather waste produced in poultry industry. In this research the crude oil of poultry feather fat was extracted by soxhlet method using hexane as a solvent. The data resulted from gas chromatography (GC) revealed these percentages for fatty acid compositions: myristic acid (3%), palmitic acid (30%), stearic acid (22%), oleic acid (8.1%), linoleic acid (3%) and arachidonic acid (7%).In this experimental research, the effects of some parameters such as alcohol to oil molar ratio (4:1,6:1, 8:1), catalyst concentration (0.75,1 and 1.25% w/w) and the transesterification reaction time(40,60 and80min) on the percentage offatty acids conversioninto methyl ester(biodiesel) are studied. The results show increasing catalyst concentration up to 1% causes the oil to biodiesel conversion percentage having an upward trend and then adownward trend byincreasing catalyst concentration up to 1.25%. With increasing molar ratio from 4:1 to 6:1 and then 8:1, oil to biodiesel conversion percentage increased16% and2%, respectively. Ultimatelythe optimum point defined by response surface method (RSM) forproducing biodiesel from feather fat is calculated catalyst concentration of 1 wt%, 7.24:1 molar ratio and in 75 minutes resulting in conversion percentage of97.62%.
    Keywords: Feather, Biodiesel, Optimization, RSM, Transesterification
  • L.E.M.C. Zaidan, G. Guimar, Atilde, Es, L.B. Santos, Y.B. Brand, Atildeo., C.M.B.M. Barbosa, M. Benachour, V.L. Silva Pages 149-156
    for quantitative analysis of compounds derived from refractory pollutants. Such methods are important for routine quality control analysis of an effluent before being discharged into the environment. Therefore, a rapid methodology for identification and quantification of some aliphatic acids is proposed. A method using High Performance Liquid Chromatography (HPLC) analysis was established for the identification and quantification of six aliphatic acids including: maleic, acetic, fumaric, malonic, succinic, and oxalic acid. Chromatographic separation was performed by a reversed phase C18 column with a mobile phase consisting of methanol and aqueous 0.1% phosphoric acid in a ratio (10:90)) with a flow of 0.75 mL min-1 in isocratic mode.The calibration curves showed excellent coefficients of determination (R2 e” 0.99) at the concentrations tested. The recoveries were 54.72 to 99.70% for spiked samples. The method is appropriate for the detection of aliphatic acids, which can be applied to monitor the effluent.
    Keywords: HPLC, Validation, Aliphatic acids, Wastewater, Effluents
  • A. Kleckerov, Aacute, H. DoČekalov, Aacute Pages 157-164
    To examine metal content of dandelion plants in relation to environmental metal levels, concentrations of Cd, Hg and Pb were analyzed in plant parts (leaves and roots) and soil samples from five sites in the city of Brno (Czech Republic), differentially impacted by pollution. Soils and plants were collected mid-April 2011. Atomic absorption spectrometry was used to determine concentrations of the studied elements. The amount of metals measured in soils and plants corresponded with the contamination load of the sampling place. The highest values of metals were found in the soil and plants sampled at Opuštěná Street, a heavily polluted locality with high traffic density situated in the city centre. Significant correlations were found between the amount of Cd in the soil and in the dandelion roots (r = 0.863) and between the amount of Pb (r = 0.870) and Hg (r = 0.828) in the soil and in the dandelion leaves. Higher Cd content was found in underground part of the plants, indicating soil contamination. The higher Hg and Pb content in leaves rather than in roots in all locations illustrated a contribution of significant atmospheric deposition. Washing the leaves before the analysis significantly reduced the measured metal concentrations. This indicated that substantial amount of metals was on the leaves surface as dry aerosol particles. Inter-metal correlations between soil, leaves and roots samples showed that the sources of Cd, Pb and Hg pollution in Brno urban areas were mainly of anthropogenic origin. The content of heavy metals both in the dandelion plant tissue and in the soil should be seen as a good indicator of natural urban environmental pollution.
    Keywords: Environmental pollution, Urban soil, Determination of metals, Inter, metal correlations, Plant monitoring
  • G. Varank, H. Erkan, S. Yaz, Yacutec., Yacute, A. Demir, G. Engin Pages 165-180
    In the present study, the treatment of tannery wastewater was performed by electrocoagulation method (EC) using aluminium and steel electrodes. Response surface methodology (RSM) with three factors; current density (I), electrolysis time (t) and pH, with each factor at five levels, was used to optimize the factors for higher chemical oxygen demand (COD) and total suspended solids (TSS) removal. Operational parameters I, t and pH were varied between 22–110 mA/cm2, 5-45 min and 3-7, respectively. For the optimal parameter values, the removal efficiency of COD and TSS attained respectively 82.2% and 85.5% for aluminium electrodes and 67.4% and 86.2% for steel electrodes. Analysis of variance (ANOVA) showed a high variance coefficient (R2) value of 0.96 and 0.81, for COD and TSS removal, respectively, thus ensuring a satisfactory adjustment of the second-order regression model with the experimental data. Corresponding energy consumption was found to be 2.92 €/m3 and 8.18 €/m3, for COD removal by using aluminium and steel electrodes, respectively.
    Keywords: Tannery wastewater, Electrocoagulation, RSM, Optimization, Cost analysis
  • T. Ceccarelli, S. Bajocco, L. Luigi Perini, L. Luca Salvati Pages 181-192
    Urban expansion and agriculture intensification are relevant drivers in Land Degradation (LD) processes in Europe due to net loss of land, soil sealing, landscape fragmentation and other negative effects on the environment. This paper explores changes (or “trajectories” of change) in land use and cover (LULC) and their relationship with the consumption of soils in Emilia-Romagna (northern Italy) over a 55-years period from 1954 to 2008, and separately over three time periods (1954-1976, 1976-1994 and 1994-2008) characterized by distinctive processes of urban and agricultural development. Four high-resolution LULC maps for 1954, 1976, 1994, and 2008 were analysed together with a 1:50,000 scale land capability map used as an indicator of soil quality. Out of an investigated area of around 12.000 km2, 34% underwent changes in LULC over the entire study period. “Agriculture internal conversions” accounted for 46% of the changes and “urban expansion” for as much as 35%. The first period was characterized by “agriculture internal conversions” associated with intensification processes. In the second period internal agricultural conversions became even more important. In the third period the most relevant conversion process was agricultural extensivation, with urban expansion also becoming relevant. During the entire period, the area consumed by urban expansion took around 41 % of the high-quality soils. Other trajectories consumed soils of lower quality, with the exception of internal agricultural conversions (accounting for another 46%). The suggested approach can provide valuable indications for assessing quantity and quality of soils taken by urban expansion, thus orienting sustainable land management.
    Keywords: Degradation, Capability, Trajectories, Agriculture, Urban
  • M. Mirzaebrahimtehrani, M. Abbaspour, J. Nouri, N. Mazloomi Pages 193-204
    Pricing for an insurance policy can be described as the process of calculation of expected compensation to be paid to property losers as well as associated costs of potential risks. Loss forecast is accurate if the risks will be identified appropriately in order to calculate the frequency and expected severity of losses.This is particularly important about environmental risks since most of them appear in the long run. Environmental risk assessment model is both able to estimate the environmental liability premium for environmental pollution and degradation, and it can play a valuable role in promoting this industry. ELIS (Environmental Liability Insurance) software calculates the environmental risk number in industry sector and insurance charges for events resulting in environmental pollution. This paper deals with designing the model and outputs of the software. The user selects the type of project, and input the descriptive information concerning the occurrence of possible environmental pollutions. The model calculates risk numbers, the type of accidents, classification and weighting of severity of environmental impacts, risk priority numbers (RPN); pollutant volume and environmental sensitivity, environmental cost of contaminates, and finally Net premium for Possible Accidents. The case study indicated the applicability of then model. For this case an oil refinery in Iran was selected with a capacity of 85,000.barrels of refined oil per day. The calculated premium on the basis of losses arising from air pollution was evaluated to be equivalent to 70,000$ US. The same procedure can be applied to evaluate the amount of premium for soil and water pollution.
    Keywords: Insurance, Compensation, Premium, Risk, Environment, Pollution, ELIS software
  • A. Vinder, M. SimoniČ, Z. Novak-PintariČ Pages 205-212
    This paper presents the development of a model for evaluating adsorbable organic halogens’ (AOX) removal efficiency during wastewater treatment by using the micellar-enhanced ultrafiltration (MEUF) technique. Surfactants can form larger aggregates (micelles) were prepared into which AOXs dissolve and are then retained by the membrane. Synthetic wastewater samples containing certain concentrations of surfactants, AOXs, and electrolytes (expressed in terms of conductivity). Regression analysis was used to examine firstly, the effect of anionic surfactants concentrations, and those of non-ionic surfactants and electrolytes on AOX removal and secondly, the effects of anionic and non-ionic surfactants removal efficiences, and electrolytes, on AOXs removal. A relationship was generated for each of the components, showing the removal of AOX as a linear functions of the concentrations of each component. The equations were validated through variance analysis. This study shows that AOXs removal efficiencies largely depend on the formation and removal of anionic surfactant micelles from the membrane. The equations obtained during this study could be used for predicting the extent to which AOXs can be removed if the input parameters are known.
    Keywords: Surfactants, AOX, Removal efficiency, MEUF, Regression analysis
  • Z. Abedi, A. Fattahi Ardakani, A.R. Hanifnejad, N. Dashti Rahmatabadi Pages 213-220
    Groundwater can be used directly or indirectly and any decline in its quality or quantity may negatively impact the environment. Through groundwater valuation, people are made aware of the fact that groundwater is not free of charge and therefore the significance of groundwater preservation is established. In this study, groundwater quality preservation value has been estimated for the city of Yazd based on the contingent valuation method (CVM). The methodology used consisted of field study and library research. After determining the sample size using Cochran’s formula, the distributed questionnaires were filled by the inhabitants of the city of Yazd. Thereafter, the results were analysed using Excel and EViews. Finally, people’s willingness to pay for the preservation of Yazd groundwater quality was estimated to be US$18.5 annually per capita, which is a remarkable value. Hence, it was determined that groundwater quality preservation was of great value to the inhabitants of Yazd.
    Keywords: Conservation value, Groundwater, Contingent valuation method (CVM), willingness to pay (WTP), Yazd
  • M. Mendizabal, J. Sep, Uacute, Lveda, P. Torp Pages 221-230
    The scientific community agrees that climate change is one of the greatest challenges that our society will have to face this century. Indeed, the fourth report from the Intergovernmental Panel on Climate Change (IPPC) confirms the certitude of this phenomenon and its impacts, which can range from droughts to floods, health problems and food shortages. The principal objective of this paper is to assess the impact of climate change on flood events and its consequences on human. This point is necessary to define and evaluate different adaptation options. Even taking into account the medium greenhouse emission scenario, according to the results, it is expected that extreme precipitation will increase during the twenty century, although there is an uncertainty in the percentage due to the climatic models. It is expected an increase in peak discharge between 14±9 and 15±8 for 3 models and for the period 2001-2040 with a return period exceeding 40 years. For the period 2041-2080 there is more uncertainty, it is expected an increase between 12±8 and 19±10 for 2 models. According to the results, changes in flood event are expected with its associated uncertainty and new flood zones are detected with greater hazard to people.
    Keywords: Flood, Climate change, Human health, Heavy precipitation, Impacts
  • H. DĄbkowska- NaskrĘt, H. Jaworska, J. DŁugosz Pages 231-236
    Limestone, exploited near Bielawy, a town located in the kujawsko-pomorskie province ofPoland, is the main raw material in the production process in a cement plant. The dust emitted by the factory is of alkaline pH and contains such heavy metals as: cadmium (Cd), lead (Pb), chromium (Cr) and nickel (Ni). The research aims at assessing the influence of cement dust on the total content and bioavailable forms of nickel in the soils adjacent to the cement plant. The material comprised the samples of luvisols, taken at different distance from the pollution emmiter, in which the following parameters were determined: pH in 1M KCl, the content of CaCO3, organic carbon and texture. The total content of nickel ranged between 1.40 and 8.70 mg/kg and as such it does not exceed the nickel content typical for non contaminated soils of the region. The content of phytoavailable forms of nickel ranged between 0.03 and 0.8 mg/kg and is considered as belowtoxicity level, yet may cause allergies. Taking into consideration the texture of the examined soils, their low buffer capacity and vulnerability to pollution it is critical to control the content of nickel and the other metals in soils surrounding the cement plant.
    Keywords: Cement, Dust, Soil, Nickel, Environment
  • C. Cantaluppi, A. Fasson, F. Ceccotto, A. Cianchi, S. Degetto Pages 237-248
    The geothermal phenomena in the area nearby the Euganean Hills (near Padua, in Italy) are known and exploited for therapeutic purposes since ancient times, and recently also for aesthetic purposes.This paper presents the first characterization of the radionuclides content in the Euganean thermal waters and mud, extended to a great number of spas. In particular the radionuclides content of both the 238U and 232Th series in water and mud samples was determined. Moreover, for the first time the transfer of 226Ra and of 228Ra from water to mud during the maturation process was demonstrated and the comparison of 226Ra and of 228Ra activity concentration between mud and water was studied. An excess of “unsupported” 222Rn in water was measured. 226Ra enrichment was observed in “mature” mud, with respect to the “raw” mud. The absorption of radium through skin from mud application was evaluated. Also, it was possible to distinguish some muds prepared from different starting materials.
    Keywords: Geochemistry, Gamma, ray spectroscopy, Thermal water, Thermal mud, Pelotherapy, Radon