Preparation and Thermal Decomposition Kinetics of Copper(II) Complex with 1-(6-Hydroxynaphthalen-2-yl) butane-1,3-dione
Abstract:
A complex of Cu(II) with 1-(6-HydroxyNaphthalen-2-yl) Butane-1,3-Dione (HNBD) was synthesized and characterized by elemental analysis, IR, UV and DTA-TG-DTG techniques. IR spectra as well as UV-visible absorption measurements indicated that Cu(II) ion was coordinated to the HNBD ligand. The TG-DTA-DTG curves showed that thermal decomposition of the anhydrous complex was a two-stage process and the residue of decomposition was CuO. The decomposition mechanism and non-isothermal kinetic parameters of the complex were obtained from the analysis of TG-DTG data using three kinds of integral methods (Coat-Redfern equation, HM equation, MKN equation) and differential method (Achar equation). The results indicate that the kinetic equations with parameters describing the thermal decomposition reaction are with E = 417.78 kJ/mol, A = 3.531038/s, S = 487.55 J/K•mol and n =3 for the first stage, with E = 88.76 kJ/mol, A = 4.74105, S = -144.59 J/K /mol and n =2 for the second stage.
Keywords:
Thermal decomposition kinetics , DTA , TG , DTG , Cu(II) complex , 1 , (6 , hydroxynaphthalen , 2 , yl) butane , 1 , 3 , dione
Language:
English
Published:
Iranian Journal of Chemistry and Chemical Engineering, Volume:32 Issue: 1, Jan-Feb 2013
Page:
49
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