Efficient synthesis of trisphenols using reduced sulfonated graphene nanocatalyst under solvent free conditions

Abstract:
This study reports a new methodology for the efficient synthesis of trisphenol compounds using the reaction of
2,6-bis(hydroxymethyl) phenols with phenols under heterogeneous conditions. A sulfonated reduced graphene oxide
(RGO-SO3H) nanocatalyst was used to promote the reaction under solvent-free conditions. A range of trisphenol compounds were produced in the presence of this catalyst system in good to excellent yields. In the presence of this catalyst system, a less amount of phenol is required, which improves the environment through its capability in synthesis of trisphenols. The
RGO-SO3H catalyst was reusable at least for 8 times in this process without a significant decrease in its catalytic activity.
Language:
English
Published:
Iranian Journal of Catalysis, Volume:6 Issue: 3, Summer 2016
Pages:
297 to 304
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