Distribution of Zn Fractons and their Relationship with Soil Properties in Some Soils of Khorasan Razavi Province

Zinc is one of the essential micronutrients for plants, mining and industrial activities leading to pollution of heavy metals, including zinc metal contamination in soils. In addition to the total concentration, knowledge of the Zinc fractions is necessary to assess the mobility of zinc in the soils. One of the sequential extraction methods is Tessier method. sequential extraction with plant cultivation simultaneously, is the appropriate approach for assessing the mobility of toxic metals. Therefore this study was conducted to evaluate the chemical forms and determine their relationship to the physical and chemical properties of soils in some fields under cultivation in Khorasan Razavi province.
The experiment was conducted in a completely randomized design with factorial arrangement includes 4 levels of contamination (0, 500, 1000 and 1500 (mg/kg)) and 10 soil types from different regions of Khorasan Razavi province of 0-30 cm depth in the range of electrical conductivity 1 up to 15 ds/m, with three replications at Research greenhouses of Ferdowsi University of Mashhad. An example of mining waste was prepared as a source of pollution. The soil samples were kept at field capacity moisture for 6 months. Then air-dried soil samples were used for planting borage and determine the Zinc fractions. Then soil samples were air dried and used for planting borage and determining the Zinc fractions. Texture, cation exchange capacity, organic carbon, electrical conductivity, pH and Available phosphorus and potassium were measured in the saturation extract. DTPA-extractable Zinc was measured by atomic absorption spectrometry. Borage was planted in greenhouses in 3 kg pots with three replications. During flowering, the plants were harvested and dry digestion method was used to measure the concentration of Zinc. Chemical forms and Pseudo total concentration of zinc in the samples were determined using Tessier and digestion by HCl and HNO3 acids (3:1) methods respectively. The concentration of the extracts was measured by atomic absorption spectrometry. Statistical analysis was done using Minitab and Excel softwares.
Chemical Forms Average of zinc in soils was as follows:Exchangeable In this study, the residual, carbonate and organic fractions are dominant form of zinc in soils, respectively. With increasing level of contamination, percentage of residual zinc decreased and percentage of other fractions increased, particularly organic and carbonate. Increasing the availability of zinc, is a threat to the environment. There is a high correlation coefficient between different fractions of Zinc with each other and with the pseudo total, amount of plant and available plant zinc showed that there is a dynamic relationship in the soil systems. There is a higher correlation coefficient between the available zinc and carbonate and organic fractions of soils, which indicate available plant zinc, are mainly derived from carbonate and organic fractions.