The Barzavand copper deposit, NW Naein, Esfahan Province: Constraints on mineralization and geochemistry of alteration system

The Barzavand copper deposit with Oligocene age located in 30 Km northeast of Zefreh along a tension fault with W-E trend and developed within basaltic lava with stratabound form. Alterations mainly include: pyritization, propylitization, zeolitization, silicification, saussuritization and uralitization of basaltic lava. Furthermore geochemical studies in Barzavand show enrichment of SiO2, Al2O3, K2O, Na2O, P2O5, TiO2, ∑REE, Ag, As, Ba, Be, Bi, Cd, Cs, Cu, Li, Mo, Nb, Pb, Rb, Sb, Se, Sn, Sr, Ta, Tl, Te, Th, U, W, Y, Zn and Zr, enrichment- depletion of CaO, Fe2O3, MnO, Hf, Sc and V and depletion of S, Ni, Cr, MgO and Co during alteration. The positive correlation between (La/Lu)N, (La/Yb)N, (La/Sm)N and (La/Y)N and CaO (r= 0.70 to 0.96) indicate propylitization of host rock basalt and increase in pH of fluid responsible for mineralization that play important role in differentiation of lanthanides in study area. Ore minerals include chalcopyrite, bornite, covellite, azurite, malachite, hematite, goethite and pyrite. Copper is transported by means of chloride complexes into oxidized brines water related to late diagenesis stage and precipitated by substitution within pyrites formed during the volcanism process. It seems that the Barzavand copper deposit has submarine volcanism, early and late diagenesis, burial metamorphism and weathering stages during its evolution. According to alteration properties, mineralogy and the whole rock geochemistry, the Barzavand copper deposit is most similar to Manto type copper deposits.