Identification and determination of amounts of polycyclic aromatic hydrocarbons in the surface soil of Nuruddin Abad in Garmsar

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous pollutants with teratogenic, mutagenic and carcinogenic potential, which can pose potential risks to the environment and human health. Therefore, this study was conducted for the analysis of PAHs compounds content in surface soil samples of the disposal site of the wastes resulting from the activity of oil refining units (Nuruddin Abad, Garmsar) in 2022.

In this research, surface soil samples were collected from 8 sampling sites in the study area. After the extraction of analytes based on the soxhlet method, the gas chromatography/flame ionization detector (GC-FID) method was used for the determination of PAHs compounds in the samples. Statistical analysis was performed using SPSS software.

The results showed that the concentrations of Naphthalene (Nap), Acenaphthene (Ace), Benzo[b]fluoranthene (BbF), Dibenz[a,h]anthracen (DBA), Benzo[g,h,i]perylene (BP) and Indeno[1,2,3‐c,d]pyren (Ind) were less than the quantification limit of the measurement method <0.01 mg/kg. total concentrations of 16 PAHs compounds ranged from 56.55 to 92.06 mg/kg.

The results showed that the concentrations of Acenaphthylene (Acy), Fluorene (Flu), Phenanthrene (Phen), Anthracene (Ant), Fluoranthene (Flt), Pyrene (Pyr), Chrysene (Chr), Benz[a]anthracene (BaA), Benzo[k]fluoranthene (BkF), Benzo[a]pyrene (BaP) were higher than MPC established by the Iranian Department of Environment. Also, the concentrations of Acy, Flu, Phen, Ant, Pyr, Chr, BaA, BkF, and BaP were higher than MPC established by MHWS. As the mean contents of some PAHs were higher than the MPC, therefore, periodic monitoring of soil contamination with PAHs is recommended for the environmental and human health aspects.